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Poly[(μ(2)-quinoline-3-carboxyl-ato-κN:O)(μ(2)-quinoline-3-carboxyl-ato-κN:O,O')cadmium].

作者信息

Wang Xing, Yan Yong-Sheng, Sun He-Yi, Wang Shen-Tang, Liu Chun-Bo

机构信息

School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m163. doi: 10.1107/S1600536812001031. Epub 2012 Jan 18.

Abstract

In the title compound, Cd(C(10)H(6)NO(2))(2), the Cd(II) atom is coordinated by three O atoms and two N atoms from four quinoline-3-carboxyl-ate (L(-)) ligands, leading to a distorted trigonal-bipyramidal geometry. The L(-) ligands link the Cd(II) atoms into a plane parallel to (100), with one ligand being tridentate, coordinating via the N atom and chelating a second Cd atom, and the other being bidentate, bridging two Cd atoms via the N and one O atom.. This two-dimensional network extends into a double-layer network by π-π inter-actions, with centroid-centroid distances of 3.680 (2) and 3.752 (2) Å. Another type of π-π inter-action between pyridine rings [centroid-centroid distance = 3.527 (2) Å] leads to a three-dimensional supra-molecular architecture.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fa6d/3274893/6c4a442bb441/e-68-0m163-fig1.jpg

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