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双（μ-2-甲基喹啉-8-醇根）-κN,O:O；κO:N,O-双-[(乙酸根-κO)(甲醇-κO)锌(II)]

Bis(μ-2-methyl-quinolin-8-olato)-κN,O:O;κO:N,O-bis-[(acetato-κO)(methanol-κO)zinc(II)].

作者信息

Sattarzadeh Elham, Mohammadnezhad Gholamhossein, Amini Mostafa M, Ng Seik Weng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 22;65(Pt 5):m554. doi: 10.1107/S1600536809014214.

DOI:10.1107/S1600536809014214
PMID:21583787
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977601/
Abstract

The reaction of zinc acetate and 2-methyl-8-hydroxy-quinoline in methanol yielded the centrosymmetric dinuclear title compound, [Zn(2)(C(10)H(8)NO)(2)(CH(3)CO(2))(2)(CH(3)OH)(2)], which has the Zn atom within a distorted NO(4) trigonal-bipyramidal coordination geometry. Methanol-acetate O-H⋯O hydrogen bonds link the dinculear units into a linear supra-molecular chain extending parallel to [100].

摘要

乙酸锌与2-甲基-8-羟基喹啉在甲醇中反应生成了中心对称的双核标题化合物[Zn₂(C₁₀H₈NO)₂(CH₃CO₂)₂(CH₃OH)₂]，其中锌原子处于扭曲的NO₄三角双锥配位几何构型中。甲醇-乙酸根O-H⋯O氢键将双核单元连接成平行于[100]方向延伸的线性超分子链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/edcd/2977601/ad623a79e729/e-65-0m554-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/edcd/2977601/ad623a79e729/e-65-0m554-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/edcd/2977601/ad623a79e729/e-65-0m554-fig1.jpg

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引用本文的文献

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