二氯（2-甲基喹啉-8-醇根-κN,O）锌酸（II）-8-羟基-2-甲基喹啉鎓甲醇溶剂合物
8-Hydr-oxy-2-methyl-quinolinium dichlorido(2-methyl-quinolin-8-olato-κN,O)zincate(II) methanol solvate.
作者信息
Sattarzadeh Elham, Mohammadnezhad Gholamhossein, Amini Mostafa M, Ng Seik Weng
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 22;65(Pt 5):m553. doi: 10.1107/S1600536809014202.
Abstract
The reaction of zinc chloride and 2-methyl-8-hydroxy-quinoline in methanol yielded the title monosolvated salt, (C(10)H(10)NO)[ZnCl(2)(C(10)H(8)NO)]·CH(3)OH, which has the Zn atom within a distorted Cl(2)NO tetra-hedral coordination geometry. Supra-molecular chains feature in the crystal structure, comprising all components of the structure stabilized by a combination of O-H⋯O, N-H⋯O and O-H⋯Cl hydrogen bonding.
摘要
氯化锌与2-甲基-8-羟基喹啉在甲醇中反应生成了标题单溶剂化盐，(C₁₀H₁₀NO)[ZnCl₂(C₁₀H₈NO)]·CH₃OH，其中锌原子处于扭曲的Cl₂NO四面体配位几何构型中。晶体结构中存在超分子链，其由结构的所有组分通过O-H⋯O、N-H⋯O和O-H⋯Cl氢键的组合而稳定化。
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