三羰基（氯二苯基锡基）{η-[2-(二甲氨基)乙基]环戊二烯基}钼
Tricarbonyl(chlorodiphenylstannyl){η-[2-(dimethylamino)ethyl]cyclopenta-dienyl}molybdenum.
作者信息
Fischer Paul J, Krohn Kristina M, Young Victor G
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 25;65(Pt 5):m558-9. doi: 10.1107/S1600536809014329.
Reaction of the tricarbon-yl{η(5)-[2-(dimethyl-amino)eth-yl]cyclo-penta-dien-yl}molybdenum anion and dichlorido-diphenyl-stannane affords the title compound, [MoSn(C(6)H(5))(2)Cl(C(9)H(14)N)(CO)(3)], which exhibits a four-legged piano-stool geometry with chlorido-diphenyl-stannyl ligands unperturbed by the pendant 2-(dimethyl-amino)ethyl groups. The Mo-Sn bond length [2.7584 (5) Å] and the distortion of the tetra-hedral tin coordination geometry are similar to those observed in related tin-substituted tricarbonyl-molybdenum and -tungsten complexes.
三羰基{η(5)-[2-(二甲基氨基)乙基]环戊二烯基}钼阴离子与二氯二苯基锡反应得到标题化合物[MoSn(C₆H₅)₂Cl(C₉H₁₄N)(CO)₃]，该化合物呈现出四足钢琴凳几何构型，其中二氯二苯基锡基配体不受2-(二甲基氨基)乙基侧链的影响。Mo-Sn键长[2.7584 (5) Å]以及四面体锡配位几何构型的畸变与在相关锡取代的三羰基钼和钨配合物中观察到的类似。
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