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羰基（η-环戊二烯基）（吡啶）（三乙基锡基）铁（II）

Carbon-yl(η-cyclo-penta-dien-yl)(pyridine)(triethyl-stann-yl)iron(II).

作者信息

Itazaki Masumi, Kamitani Masahiro, Nakazawa Hiroshi

机构信息

Department of Chemistry, Graduate School of Science, Osaka City University, Sumiyoshi-ku, Osaka 558-8585, Japan.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 20;64(Pt 12):m1578. doi: 10.1107/S1600536808037781.

DOI:10.1107/S1600536808037781
PMID:21581180
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2959867/
Abstract

In the title complex, [Fe(C(5)H(5)){Sn(C(2)H(5))(3)}(C(5)H(5)N)(CO)], the Fe atom is coordinated by carbonyl, pyridine, triethyl-stannyl and cyclo-penta-dienyl ligands in a typical three-legged piano-stool configuration. The Fe-Sn and Fe-N bond distances are 2.5455 (13) and 1.984 (6) Å, respectively.

摘要

在标题配合物[Fe(C₅H₅){Sn(C₂H₅)₃}(C₅H₅N)(CO)]中，铁原子通过羰基、吡啶、三乙基锡基和环戊二烯基配体以典型的三足钢琴凳构型配位。Fe-Sn和Fe-N键长分别为2.5455 (13) Å和1.984 (6) Å。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43d8/2959867/42ff2fbf551c/e-64-m1578-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43d8/2959867/42ff2fbf551c/e-64-m1578-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43d8/2959867/42ff2fbf551c/e-64-m1578-fig1.jpg

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