Wang Shou-Yu, Yuan Liang, Xu Liang, Zhang Zhen, Diao Yun-Peng, Lv De-Cheng
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 30;65(Pt 5):o1154. doi: 10.1107/S1600536809015165.
The two mol-ecules in the asymmetric unit of the title compound, C(20)H(19)N(3)O(4)·CH(4)O, are paired via O-H⋯(O,N), N-H⋯O, and C-H⋯O hydrogen bonds. The mol-ecular skeleton of the acetohydrazide mol-ecule is close to planar; the benzene and quinoline mean planes form a dihedral angle of 3.9 (3)°. The crystal packing exhibits weak inter-molecular C-H⋯O hydrogen bonds and π-π inter-actions, indicated by short distances of 3.668 (3) Å, between the centroids of N-containing six-membered rings from neighbouring acetohydrazide mol-ecules.
标题化合物C(20)H(19)N(3)O(4)·CH(4)O不对称单元中的两个分子通过O-H⋯(O,N)、N-H⋯O和C-H⋯O氢键配对。乙酰肼分子的分子骨架接近平面;苯环和喹啉平均平面形成的二面角为3.9 (3)°。晶体堆积表现出弱的分子间C-H⋯O氢键和π-π相互作用,相邻乙酰肼分子含氮六元环的质心之间的短距离为3.668 (3) Å表明了这一点。