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（E）-N'-（4-羟基-亚苄基）-4-羟基-苯甲酰肼甲醇溶剂化物

(E)-N'-(4-Hydroxy-benzyl-idene)-4-hydroxy-benzohydrazide methanol solvate.

作者信息

Li Cong-Ming, Ban Hong-Yan

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 6;65(Pt 7):o1465. doi: 10.1107/S1600536809020078.

DOI:10.1107/S1600536809020078
PMID:21582768
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969426/
Abstract

The title compound, C(14)H(12)N(2)O(3)·CH(4)O, consists of a Schiff base mol-ecule and a methanol mol-ecule of crystallization. The Schiff base mol-ecule is nearly planar, the dihedral angle between the planes of the two benzene rings being 7.2 (2)°. The mol-ecule exists in the trans configuration with respect to the methyl-idene unit. In the crystal structure, the Schiff base and methanol mol-ecules are linked through O-H⋯O, N-H⋯O and O-H⋯N hydrogen bonds, forming a three-dimensional network.

摘要

标题化合物C(14)H(12)N(2)O(3)·CH(4)O由一个席夫碱分子和一个结晶甲醇分子组成。席夫碱分子近乎平面，两个苯环平面之间的二面角为7.2 (2)°。该分子相对于亚甲基单元呈反式构型。在晶体结构中，席夫碱和甲醇分子通过O-H⋯O、N-H⋯O和O-H⋯N氢键相连，形成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9c8c/2969426/9235c4208961/e-65-o1465-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9c8c/2969426/dd6dd99f5655/e-65-o1465-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9c8c/2969426/9235c4208961/e-65-o1465-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9c8c/2969426/dd6dd99f5655/e-65-o1465-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9c8c/2969426/9235c4208961/e-65-o1465-fig2.jpg

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本文引用的文献

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Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 28;65(Pt 4):o883. doi: 10.1107/S1600536809010435.
2
(E)-N'-[1-(2-Hydroxy-phen-yl)ethyl-idene]-3-methoxy-benzohydrazide.（E）-N'-[1-（2-羟基苯基）亚乙基]-3-甲氧基苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 28;65(Pt 4):o876. doi: 10.1107/S1600536809010228.
3
(E)-N'-(5-Bromo-2-methoxy-benzyl-idene)-4-methoxy-benzohydrazide.（E）-N'-（5-溴-2-甲氧基-亚苄基）-4-甲氧基-苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 8;64(Pt 12):o2260. doi: 10.1107/S1600536808035472.
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(E)-N'-(2-Chloro-5-nitro-benzyl-idene)-4-methoxy-benzohydrazide.（E）-N'-（2-氯-5-硝基-亚苄基）-4-甲氧基-苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 25;64(Pt 11):o2177. doi: 10.1107/S1600536808034107.
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3-Bromo-N'-[(E)-4-hydroxy-benzyl-idene]benzohydrazide.3-溴-N'-[(E)-4-羟基-亚苄基]苯甲酰肼
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