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二氯双[2-(2-呋喃基)-1-(2-呋喃甲基)-1H-苯并咪唑-κN]镉(II)

Dichloridobis[2-(2-fur-yl)-1-(2-furylmeth-yl)-1H-benzimidazole-κN]cadmium(II).

作者信息

Wang Xia, Li Yu-Xian, Liu Yan-Ju, Yang Huai-Xia, Zhang Cong-Cong

机构信息

Pharmacy College, Henan University of Traditional Chinese Medicine, Zhengzhou 450008, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 4;66(Pt 10):m1207. doi: 10.1107/S1600536810034409.

DOI:10.1107/S1600536810034409
PMID:21587366
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2983315/
Abstract

In the title complex, [CdCl(2)(C(16)H(12)N(2)O(2))(2)], the Cd(II) ion exhibits site symmetry 2. It shows a distorted tetra-hedral coordination defined by two N atoms from symmetry-related 2-(2-fur-yl)-1-(2-furylmeth-yl)-1H-benzimidazole ligands and by two symmetry-related Cl atoms. Intra-molecular C-H⋯O hydrogen bonds stabilize the mol-ecular configuration. Adjacent mol-ecules are linked through C-H⋯Cl hydrogen bonds into a network structure.

摘要

在标题配合物[CdCl₂(C₁₆H₁₂N₂O₂)₂]中，Cd(II)离子呈现出2次轴对称性。它具有由来自对称相关的2-(2-呋喃基)-1-(2-呋喃甲基)-1H-苯并咪唑配体的两个N原子以及两个对称相关的Cl原子所定义的扭曲四面体配位。分子内的C—H⋯O氢键稳定了分子构型。相邻分子通过C—H⋯Cl氢键连接成网络结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8d6f/2983315/149f2c231a78/e-66-m1207-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8d6f/2983315/149f2c231a78/e-66-m1207-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8d6f/2983315/149f2c231a78/e-66-m1207-fig1.jpg

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