高氯酸（二甲基甲酰胺-κO）（2-羟基苯甲酸根-κO，O）[三（1-甲基-1H-苯并咪唑-2-基甲基-κN）胺-κN]锰（II）二甲基甲酰胺单溶剂合物
(Dimethyl-formamide-κO)(2-hy-droxy-benzoato-κO,O)[tris-(1-methyl-1H-benzimidazol-2-ylmethyl-κN)amine-κN]manganese(II) perchlorate dimethyl-formamide monosolvate.
作者信息
Wu Huilu, Bai Ying, Huang Xingcai, Meng Xuan, Qi Baoliang
机构信息
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 11;66(Pt 10):m1252. doi: 10.1107/S160053681003610X.
In the title complex, [Mn(C(7)H(5)O(3))(C(27)H(27)N(7))(C(3)H(7)NO)]ClO(4)·C(3)H(7)NO, the Mn(II) ion is coordinated in a slightly distorted monocapped trigonal-prismatic geometry. The tris-(1-methyl-1H-benzimidazol-2-ylmeth-yl)amine (Mentb) ligand coordinates in a tetra-dentate mode and the coordination is completed by a bis-chelating salicylate ligand and a dimethyl-formamide ligand. The hy-droxy group and the ortho H atoms of the salicylate ligand were refined as disordered over two sites with occupancies of 0.581 (8) and 0.419 (8). Both disorder components of the hy-droxy group form intra-molecular O-H⋯O hydrogen bonds.
在标题配合物[Mn(C₇H₅O₃)(C₂₇H₂₇N₇)(C₃H₇NO)]ClO₄·C₃H₇NO中，Mn(II)离子以略微扭曲的单帽三角棱柱几何构型配位。三（1-甲基-1H-苯并咪唑-2-基甲基）胺（Mentb）配体以四齿模式配位，配位由双螯合水杨酸盐配体和二甲基甲酰胺配体完成。水杨酸盐配体的羟基和邻位H原子在两个位置上无序精制，占有率分别为0.581(8)和0.419(8)。羟基的两个无序组分均形成分子内O-H⋯O氢键。
Zotero 插件