Wu Huilu, Jia Fei, Kong Jin, Kou Fan, Yuan Jingkun
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 18;66(Pt 10):m1270. doi: 10.1107/S1600536810036457.
In the title complex, [Mn(C(4)H(5)O(2))(C(27)H(27)N(7))(C(3)H(7)NO)]ClO(4)·C(3)H(7)NO, the Mn(II) ion is seven-coordinated in a distorted monocapped trigonal-prismatic geometry formed by a tetra-dentate tris-(1-methyl-1H-benzimidazol-2-ylmeth-yl)amine mol-ecule, a bidentate 2-methacrylate anion and a dimethyl-formamide mol-ecule. The methyl groups of the coordinated dimethyl-formamide mol-ecule and the perchlorate anions are disordered over two positions with occupancy factors of 0.640 (8) and 0.360 (8).
在标题配合物[Mn(C₄H₅O₂)(C₂₇H₂₇N₇)(C₃H₇NO)]ClO₄·C₃H₇NO中，Mn(II)离子由一个四齿的三（1 - 甲基 - 1H - 苯并咪唑 - 2 - 基甲基）胺分子、一个双齿的2 - 甲基丙烯酸根阴离子和一个二甲基甲酰胺分子形成扭曲的单帽三角棱柱几何构型，呈七配位。配位的二甲基甲酰胺分子的甲基和高氯酸根阴离子在两个位置上无序，占有率分别为0.640 (8)和0.360 (8)。
