二-μ-叠氮基-双-({N'-[1-(2-吡啶基-κN)亚乙基]乙酰肼基-κN',O}二铜(II))
Di-μ-azido-bis-({N'-[1-(2-pyrid-yl-κN)ethyl-idene]acetohydrazidato-κN',O}dicopper(II)).
作者信息
Datta Amitabha, Das Kuheli, Jhou Yan-Ming, Huang Jui-Hsien, Lee Hon Man
机构信息
National Changhua University of Education, Department of Chemistry, Changhua, Taiwan 50058.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 18;66(Pt 10):m1271. doi: 10.1107/S1600536810034860.
The dimeric title compound, [Cu(2)(C(9)H(10)N(3)O)(2)(N(3))(2)], is located on a crystallographic inversion center. The Cu atom is coordinated by a tridentate anionic hydrazone ligand and two bridging azide ligands in a distorted square-pyramidal coordination geometry. The non-bonding Cu⋯Cu distance is 3.238 (1) Å. Non-classical inter-molecular C-H⋯N hydrogen bonds link the dimers into chains along the c axis.
二聚体标题化合物[Cu₂(C₉H₁₀N₃O)₂(N₃)₂]位于一个晶体学倒转中心上。铜原子由一个三齿阴离子腙配体和两个桥连叠氮配体以扭曲的四方锥配位几何构型配位。非键合的Cu⋯Cu距离为3.238 (1) Å。非经典的分子间C—H⋯N氢键将二聚体沿c轴连接成链。
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