二氯{N'-[(吡啶-2-基)亚甲基-κN]乙酰肼-κN',O}铜(II)
Dichlorido{N'-[(pyridin-2-yl)methyl-idene-κN]acetohydrazide-κN',O}copper(II).
作者信息
Datta Amitabha, Sheu Shiann-Cherng, Liu Pei-Hsin, Huang Jui-Hsien
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1852. doi: 10.1107/S1600536811049671. Epub 2011 Nov 30.
In the title compound, [CuCl(2)(C(8)H(9)N(3)O)], the Cu(II) atom has a distorted square-pyramidal CuCl(2)N(2)O coordination geometry. The tridentate acetohydrazide ligand occupies three basal positions, the fourth basal position being defined by a chloride anion at a distance of 2.2116 (6) Å. The second chloride anion is in the apical position and forms a longer Cu-Cl distance of 2.4655 (7) Å. Inter-molecular N-H⋯Cl hydrogen bonds are present in the crystal, leading to the formation of chains along [10[Formula: see text]].
在标题化合物[CuCl₂(C₈H₉N₃O)]中，Cu(II)原子具有扭曲的四方锥CuCl₂N₂O配位几何构型。三齿乙酰肼配体占据三个基底位置，第四个基底位置由一个距离为2.2116 (6) Å的氯阴离子确定。第二个氯阴离子处于顶端位置，形成更长的Cu-Cl距离2.4655 (7) Å。晶体中存在分子间N-H⋯Cl氢键，导致沿[10[化学式：见原文]]形成链状结构。
Zotero 插件