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(2-氨基苯甲酸根-κO,O')(外消旋-5,5,7,12,12,14-六甲基-1,4,8,11-四氮杂环十四烷-κN,N',N'',N''')高氯酸镍(II)一水合物

(2-Amino-benzoato-κO,O')(rac-5,5,7,12,12,14-hexa-methyl-1,4,8,11-tetra-aza-cyclo-tetra-decane-κN,N',N'',N''')nickel(II) perchlorate monohydrate.

作者信息

Ou Guang-Chuan, Ng Seik Weng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 25;66(Pt 10):m1295-6. doi: 10.1107/S1600536810037116.

Abstract

In the title salt, [Ni(C(7)H(6)NO(2))(C(16)H(36)N(4))]ClO(4)·H(2)O, the Ni(II) cation is O,O'-chelated by the benzoate anion and N,N',N'',N'''-chelated by the macrocycle ligand, confering a distorted octa-hedral geometry on the metal atom. The complex cations, perchlorate anions and uncoordinated water mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds into a three-dimensional network. The perchlorate ion is disordered over two positions in a 0.554 (8):0.446 (8) ratio.

摘要

在标题盐[Ni(C₇H₆NO₂)(C₁₆H₃₆N₄)]ClO₄·H₂O中,Ni(II)阳离子通过苯甲酸根阴离子进行O,O'-螯合,并通过大环配体进行N,N',N'',N'''-螯合,赋予金属原子一个扭曲的八面体几何构型。配合物阳离子、高氯酸根阴离子和未配位的水分子通过N-H⋯O和O-H⋯O氢键连接成三维网络。高氯酸根离子在两个位置上无序分布,比例为0.554 (8):0.446 (8)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db98/2983378/375f8bd134f4/e-66-m1295-fig1.jpg

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