Ou Guang-Chuan, Ng Seik Weng
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 25;66(Pt 10):m1295-6. doi: 10.1107/S1600536810037116.
In the title salt, [Ni(C(7)H(6)NO(2))(C(16)H(36)N(4))]ClO(4)·H(2)O, the Ni(II) cation is O,O'-chelated by the benzoate anion and N,N',N'',N'''-chelated by the macrocycle ligand, confering a distorted octa-hedral geometry on the metal atom. The complex cations, perchlorate anions and uncoordinated water mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds into a three-dimensional network. The perchlorate ion is disordered over two positions in a 0.554 (8):0.446 (8) ratio.
在标题盐[Ni(C₇H₆NO₂)(C₁₆H₃₆N₄)]ClO₄·H₂O中，Ni(II)阳离子通过苯甲酸根阴离子进行O,O'-螯合，并通过大环配体进行N,N',N'',N'''-螯合，赋予金属原子一个扭曲的八面体几何构型。配合物阳离子、高氯酸根阴离子和未配位的水分子通过N-H⋯O和O-H⋯O氢键连接成三维网络。高氯酸根离子在两个位置上无序分布，比例为0.554 (8):0.446 (8)。
