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一水合高氯酸（肉桂酸根-κ(2)O,O'）（5,5,7,12,12,14-六甲基-1,4,8,11-四氮杂环十四烷-κ(4)N,N',N'',N'''）镍(II)

(Cinnamato-κ(2)O,O')(5,5,7,12,12,14-hexa-methyl-1,4,8,11-tetra-aza-cyclo-tetra-decane-κ(4)N,N',N'',N''')nickel(II) perchlorate monohydrate.

作者信息

Gao Qiang, Cao Yi-Cheng

机构信息

School of Bioscience and Bioengineering, South China University of Technology, Guangzhou Guangdong 510006, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1100. doi: 10.1107/S1600536812032175. Epub 2012 Jul 21.

DOI:10.1107/S1600536812032175
PMID:22904757
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3414150/
Abstract

In the title compound, [Ni(C(9)H(7)O(2))(C(16)H(36)N(4))]ClO(4)·H(2)O, the macrocyclic 5,5,7,12,12,14-hexa-methyl-1,4,8,11-tetra-aza-cyclo-tetra-decane ligand (L) folds around the Ni(II) atom, which is also chelated by the carboxyl-ate group. The geometry is a distorted N(4)O(2) octa-hedron. In the crystal, adjacent mol-ecules are connected by O-H⋯O and N-H⋯O hydrogen bonds into a zigzag chain parallel to [010].

摘要

在标题化合物[Ni(C₉H₇O₂)(C₁₆H₃₆N₄)]ClO₄·H₂O中，大环5,5,7,12,12,14-六甲基-1,4,8,11-四氮杂环十四烷配体（L）围绕Ni(II)原子折叠，该Ni(II)原子也被羧酸根基团螯合。其几何构型为扭曲的N₄O₂八面体。在晶体中，相邻分子通过O—H⋯O和N—H⋯O氢键连接成平行于[010]的锯齿链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e28/3414150/b3a08e4e8c51/e-68-m1100-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e28/3414150/8ee90a089d12/e-68-m1100-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e28/3414150/9b0d8ff948ff/e-68-m1100-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e28/3414150/b3a08e4e8c51/e-68-m1100-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e28/3414150/8ee90a089d12/e-68-m1100-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e28/3414150/9b0d8ff948ff/e-68-m1100-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e28/3414150/b3a08e4e8c51/e-68-m1100-fig3.jpg

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本文引用的文献

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