Liu Meiduo, Su Zhanhua, Shang Yongchen
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 30;66(Pt 10):m1308. doi: 10.1107/S1600536810037414.
The title compound, (C(3)H(5)N(2))(4)[As(6)CuMo(6)O(30)], is made up of a centrosymmetric anionic cluster and four imidazolium cations. In the cluster, the central Cu(II) atom is six-coordinated and lies on an inversion center. Adjacent clusters are linked via N-H⋯O hydrogen bonds between the imidazole cations and polyoxidoanions into a three-dimensional supra-molecular architecture.
标题化合物(C(3)H(5)N(2))(4)[As(6)CuMo(6)O(30)]由一个中心对称的阴离子簇和四个咪唑阳离子组成。在该簇中,中心Cu(II)原子为六配位且位于一个反演中心上。相邻的簇通过咪唑阳离子与多氧化阴离子之间的N-H⋯O氢键连接成三维超分子结构。