Liu Ying, Zhang Xianxi, Xue Zechun, Sheng Jian
College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 5;66(Pt 7):m756-7. doi: 10.1107/S1600536810020775.
In the title compound, [Co(C(10)H(8)N(2))(3)][Mo(6)O(19)], the Co(2+) cation is surrounded in a distorted octa-hedral coordination by six N atoms from three 2,2'-bipyridine ligands. The distribution of Mo-O bond lengths in the Lindqvist isopolyanion is consistent with other structures containing the same unit. In the crystal, the cations and anions are linked by C-H⋯O inter-actions.
在标题化合物[Co(C₁₀H₈N₂)₃][Mo₆O₁₉]中，Co²⁺阳离子被来自三个2,2'-联吡啶配体的六个N原子以扭曲的八面体配位方式包围。Lindqvist异多阴离子中Mo - O键长的分布与包含相同单元的其他结构一致。在晶体中，阳离子和阴离子通过C - H⋯O相互作用相连。
