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(2E)-2-苄叉基-5,6-二甲氧基茚满-1-酮

(2E)-2-Benzyl-idene-5,6-dimethoxy-indan-1-one.

作者信息

Ali Mohamed Ashraf, Ismail Rusli, Tan Soo Choon, Yeap Chin Sing, Fun Hoong-Kun

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 11;66(Pt 10):o2531-2. doi: 10.1107/S1600536810035695.

Abstract

The mol-ecular structure of the title compound, C(18)H(16)O(3), is roughly planar; the maximum deviation of the indanone ring system is 0.027 (1) Å and it makes a dihedral angle of 2.69 (3)° with the phenyl ring. The torsion angles between the two meth-oxy groups and the -indanone ring are -14.67 (11) and -1.11 (12)°. In the crystal, mol-ecules are connected into a ribbon along the a axis via weak inter-molecular C-H⋯O hydrogen bonds. Weak inter-molecular C-H⋯π and π-π [centroid-centroid distance = 3.7086 (6) Å] inter-actions are also observed.

摘要

标题化合物C(18)H(16)O(3)的分子结构大致呈平面状;茚满酮环系的最大偏差为0.027 (1) Å,它与苯环的二面角为2.69 (3)°。两个甲氧基与茚满酮环之间的扭转角分别为 -14.67 (11)° 和 -1.11 (12)°。在晶体中,分子通过弱分子间C-H⋯O氢键沿a轴连接成一条链。还观察到弱分子间C-H⋯π和π-π [质心-质心距离 = 3.7086 (6) Å] 相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f4bd/2983266/a5e178f5a840/e-66-o2531-fig1.jpg

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