Marouani Houda, Rzaigui Mohamed, Al-Deyab Salem S
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 25;66(Pt 10):o2613. doi: 10.1107/S1600536810037001.
In the title compound, C(10)H(16)N(2) (2+)·2HSO(4) (-), the S atoms adopt slightly distorted tetra-hedral geometry and the diprotonated piperazine ring adopts a chair conformation. In the crystal, the 1-phenyl-piperazine-1,4-diium cations are anchored between chains formed by the sulfate entities via inter-molecular bifurcated N-H⋯(O,O) and weak C-H⋯O hydrogen bonds. These hydrogen bonds contribute to the cohesion and stability of the network of the crystal structure.
在标题化合物C(10)H(16)N(2)(2+)·2HSO(4)(-)中,硫原子采取略微扭曲的四面体几何构型,双质子化的哌嗪环采取椅式构象。在晶体中,1-苯基-哌嗪-1,4-二铵阳离子通过分子间分叉的N-H⋯(O,O)和弱C-H⋯O氢键锚定在由硫酸根实体形成的链之间。这些氢键有助于晶体结构网络的凝聚和稳定性。