Kefi Riadh, Lefebvre Frédéric, Zeller Matthias, Ben Nasr Cherif
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m410. doi: 10.1107/S1600536811007562. Epub 2011 Mar 9.
In the title compound, (C(12)H(20)N(2))[ZnCl(4)]·H(2)O, the two piperazine N atoms are protonated and the ZnCl(4) anions adopt a slightly distorted tetra-hedral configuration. In the crystal, O-H⋯Cl hydrogen bonds link the tetra-chloridozincate anions and the water mol-ecules into corrugated inorganic chains parallel to [010]. The crystal structure is stabilized by N-H⋯Cl, N-H⋯O and O-H⋯Cl hydrogen bonds, with the N-H hydrogen bond originating from one of the two N atoms being trifurcated.
在标题化合物(C₁₂H₂₀N₂)[ZnCl₄]·H₂O中,两个哌嗪氮原子被质子化,[ZnCl₄]²⁻阴离子呈略微扭曲的四面体构型。在晶体中,O—H⋯Cl氢键将四氯锌酸根阴离子和水分子连接成平行于[010]的波纹状无机链。晶体结构通过N—H⋯Cl、N—H⋯O和O—H⋯Cl氢键得以稳定,其中源自两个氮原子之一的N—H氢键呈三叉状。