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一水合四氯锌酸-1-(2,5-二甲基苯基)哌嗪-1,4-二铵

1-(2,5-Dimethyl-phen-yl)piperazine-1,4-diium tetra-chloridozincate monohydrate.

作者信息

Kefi Riadh, Lefebvre Frédéric, Zeller Matthias, Ben Nasr Cherif

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m410. doi: 10.1107/S1600536811007562. Epub 2011 Mar 9.

DOI:10.1107/S1600536811007562
PMID:21753942
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3099933/
Abstract

In the title compound, (C(12)H(20)N(2))[ZnCl(4)]·H(2)O, the two piperazine N atoms are protonated and the ZnCl(4) anions adopt a slightly distorted tetra-hedral configuration. In the crystal, O-H⋯Cl hydrogen bonds link the tetra-chloridozincate anions and the water mol-ecules into corrugated inorganic chains parallel to [010]. The crystal structure is stabilized by N-H⋯Cl, N-H⋯O and O-H⋯Cl hydrogen bonds, with the N-H hydrogen bond originating from one of the two N atoms being trifurcated.

摘要

在标题化合物（C₁₂H₂₀N₂）[ZnCl₄]·H₂O中，两个哌嗪氮原子被质子化，[ZnCl₄]²⁻阴离子呈略微扭曲的四面体构型。在晶体中，O—H⋯Cl氢键将四氯锌酸根阴离子和水分子连接成平行于[010]的波纹状无机链。晶体结构通过N—H⋯Cl、N—H⋯O和O—H⋯Cl氢键得以稳定，其中源自两个氮原子之一的N—H氢键呈三叉状。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c9cf/3099933/4fa96c46694c/e-67-0m410-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c9cf/3099933/055981e813a5/e-67-0m410-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c9cf/3099933/92a3ba77c709/e-67-0m410-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c9cf/3099933/4fa96c46694c/e-67-0m410-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c9cf/3099933/055981e813a5/e-67-0m410-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c9cf/3099933/92a3ba77c709/e-67-0m410-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c9cf/3099933/4fa96c46694c/e-67-0m410-fig3.jpg

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