二甲基氯化铵铁（III）18-冠-6包合物
Dimethyl-ammonium tetra-chloridoferrate(III) 18-crown-6 clathrate.
作者信息
Shi Ping Ping, Zhao Min Min
机构信息
Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 5;66(Pt 7):m728. doi: 10.1107/S1600536810020192.
The reaction of dimethyl-amine hydro-chloride, 18-crown-6 and ferric chloride in ethanol yields the title compound, (C(2)H(8)N)[FeCl(4)]·C(12)H(24)O(6), which exhibits an unusual supramolecular structure. The protonated dimethyl-amine contains one NH(2) (+) group, resulting in a 1:1 supra-molecular rotator-stator structure (CH(3)-NH(2) (+)-CH(3))(18-crown-6), through N-H⋯O hydrogen-bonding inter-actions between the ammonium group of the cation and the O atoms of the crown ether. In the crystal, all three components lie on a common crystallographic mirror plane normal to [010].
二甲胺盐酸盐、18-冠-6与氯化铁在乙醇中反应生成标题化合物(C₂H₈N)[FeCl₄]·C₁₂H₂₄O₆，该化合物呈现出一种不寻常的超分子结构。质子化的二甲胺含有一个NH₂⁺基团，通过阳离子铵基团与冠醚的O原子之间的N-H⋯O氢键相互作用，形成了1:1的超分子旋转体-定子结构(CH₃-NH₂⁺-CH₃)(18-冠-6)。在晶体中，所有三种组分位于垂直于[010]的公共晶体学镜面平面上。
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