4-氟苯胺四氯合铁(III) 18-冠-6包合物
4-Fluoro-anilinium tetra-chloridoferrate(III) 18-crown-6 clathrate.
作者信息
Ge Jia-Zhen, Zhao Min-Min
机构信息
Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 5;66(Pt 7):m739. doi: 10.1107/S160053681002009X.
The reaction of 4-fluoro-aniline hydro-chloride, 18-crown-6 and ferric chloride in methano-lic solution yields the title compound, (C(6)H(7)FN)[FeCl(4)]·C(12)H(24)O(6), which has an unusual supramolecular structure. N-H⋯O hydrogen-bonding inter-actions between the NH(3) (+) substituents of the 4-fluoro-anilinium cations and the O atoms of the crown ether mol-ecules result in a rotator-stator-like structure.
4-氟苯胺盐酸盐、18-冠-6与氯化铁在甲醇溶液中反应生成标题化合物(C₆H₇FN)[FeCl₄]·C₁₂H₂₄O₆，其具有不寻常的超分子结构。4-氟苯胺阳离子的NH₃⁺取代基与冠醚分子的O原子之间的N-H⋯O氢键相互作用导致了一种类似转子-定子的结构。
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