二氯甲烷倍半溶剂合物氯代（2,3,7,8,12,13,17,18-八乙基-卟啉）铁（III）
Chlorido(2,3,7,8,12,13,17,18-octa-ethyl-porphyrinato)iron(III) dichloro-methane sesquisolvate.
作者信息
Safo Martin K, Buentello Kristin E, Oliver Allen G, Scheidt W Robert
机构信息
Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556-5670, USA.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 5;66(Pt 7):m733. doi: 10.1107/S1600536810020015.
The title mol-ecule, [Fe(C(36)H(44)N(4))Cl]·1.5CH(2)Cl(2), is a high-spin square-pyramidal iron(III) porphyrinate with an average value for the equatorial Fe-N bond lengths of 2.065 (3) Å and an axial Fe-Cl distance of 2.2430 (13) Å. The iron cation is displaced by 0.518 (1) Å from the 24-atom mean plane of the porphyrin ring. These values are typical for high-spin iron(III) porphyrinates.
标题分子[Fe(C₃₆H₄₄N₄)Cl]·1.5CH₂Cl₂是一种高自旋四方锥型铁(III)卟啉配合物，其赤道面Fe-N键长的平均值为2.065(3) Å，轴向Fe-Cl距离为2.2430(13) Å。铁阳离子相对于卟啉环的24原子平均平面位移了0.518(1) Å。这些值是高自旋铁(III)卟啉配合物的典型值。
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