Safo Martin K, Buentello Kristin E, Oliver Allen G, Scheidt W Robert
Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556-5670, USA.
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 5;66(Pt 7):m733. doi: 10.1107/S1600536810020015.
The title mol-ecule, [Fe(C(36)H(44)N(4))Cl]·1.5CH(2)Cl(2), is a high-spin square-pyramidal iron(III) porphyrinate with an average value for the equatorial Fe-N bond lengths of 2.065 (3) Å and an axial Fe-Cl distance of 2.2430 (13) Å. The iron cation is displaced by 0.518 (1) Å from the 24-atom mean plane of the porphyrin ring. These values are typical for high-spin iron(III) porphyrinates.
标题分子[Fe(C₃₆H₄₄N₄)Cl]·1.5CH₂Cl₂是一种高自旋四方锥型铁(III)卟啉配合物，其赤道面Fe-N键长的平均值为2.065(3) Å，轴向Fe-Cl距离为2.2430(13) Å。铁阳离子相对于卟啉环的24原子平均平面位移了0.518(1) Å。这些值是高自旋铁(III)卟啉配合物的典型值。
