乙酸根-水-{4,4',6,6'-四叔丁基-2,2'-[(2-吡啶基甲基)亚氨基二亚甲基]二酚根合}锰(III)乙醇溶剂合物
Acetato-aqua-{4,4',6,6'-tetra-tert-butyl-2,2'-[(2-pyridyl-meth-yl)imino-dimethyl-ene]diphenolato}manganese(III) ethanol solvate.
作者信息
Chard Elliott, Dawe Louise N, Kozak Christopher M
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):m771. doi: 10.1107/S1600536810021288.
Abstract
In the title complex, [Mn(C(36)H(50)N(2)O(2))(CH(3)COO)(H(2)O)]·CH(3)CH(2)OH, the Mn(III) atom is in an octa-hedral environment and is coordinated by the tetra-dentate amine-bis-(phenolate) ligand, a monodentate acetate anion and a water mol-ecule. An ethanol solvent mol-ecule is also found in the asymmetric unit. The structure displays O-H⋯O and C-H⋯O hydrogen bonding.
摘要
在标题配合物[Mn(C₃₆H₅₀N₂O₂)(CH₃COO)(H₂O)]·CH₃CH₂OH中，锰(III)原子处于八面体环境，由四齿胺-双-(酚盐)配体、一个单齿乙酸根阴离子和一个水分子配位。在不对称单元中还发现了一个乙醇溶剂分子。该结构呈现出O-H⋯O和C-H⋯O氢键。
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