Zhou Jia, Shu Mouhai
State Key Laboratory of Metal Matrix Composites, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):m399. doi: 10.1107/S1600536812007970. Epub 2012 Mar 10.
In the structure of the title complex, [Ni(CH(3)CO(2))(C(14)H(23)N(5)O)(H(2)O)]ClO(4)·H(2)O, the Ni(II) centre has a distorted octa-hedral environment defined by one O and three N atoms derived from the tetra-dentate ligand, and two O atoms, one from a water mol-ecule and the other from an acetate anion. The mol-ecules are connected into a three-dimensional architecture by O-H⋯O hydrogen bonds. The perchlorate anion is disordered over two positions; the major component has a site-occupancy factor of 0.525 (19).
在标题配合物[Ni(CH₃CO₂)(C₁₄H₂₃N₅O)(H₂O)]ClO₄·H₂O的结构中，Ni(II)中心具有一个扭曲的八面体环境，由来自四齿配体的一个O原子和三个N原子以及两个O原子界定，其中一个O原子来自水分子，另一个来自醋酸根阴离子。分子通过O—H⋯O氢键连接成三维结构。高氯酸根阴离子在两个位置上无序；主要组分的占位因子为0.525 (19)。
