一水合高氯酸（乙酸根 - κO）（水 - κO）（2 - {双 - [(3,5 - 二甲基 - 1H - 吡唑 - 1 - 基 - κN(2))甲基]氨基 - κN}乙醇 - κO）镍（II）
(Acetato-κO)(aqua-κO)(2-{bis-[(3,5-dimethyl-1H-pyrazol-1-yl-κN(2))methyl]amino-κN}ethanol-κO)nickel(II) perchlorate monohydrate.
作者信息
Zhou Jia, Shu Mouhai
机构信息
State Key Laboratory of Metal Matrix Composites, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):m399. doi: 10.1107/S1600536812007970. Epub 2012 Mar 10.
In the structure of the title complex, [Ni(CH(3)CO(2))(C(14)H(23)N(5)O)(H(2)O)]ClO(4)·H(2)O, the Ni(II) centre has a distorted octa-hedral environment defined by one O and three N atoms derived from the tetra-dentate ligand, and two O atoms, one from a water mol-ecule and the other from an acetate anion. The mol-ecules are connected into a three-dimensional architecture by O-H⋯O hydrogen bonds. The perchlorate anion is disordered over two positions; the major component has a site-occupancy factor of 0.525 (19).
在标题配合物[Ni(CH₃CO₂)(C₁₄H₂₃N₅O)(H₂O)]ClO₄·H₂O的结构中，Ni(II)中心具有一个扭曲的八面体环境，由来自四齿配体的一个O原子和三个N原子以及两个O原子界定，其中一个O原子来自水分子，另一个来自醋酸根阴离子。分子通过O—H⋯O氢键连接成三维结构。高氯酸根阴离子在两个位置上无序；主要组分的占位因子为0.525 (19)。
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