（2-甲氧基苄基）（2-甲氧基亚苄基）氮鎓（2-甲氧基苯基）甲铵四氯锌酸（II）一水合物
(2-Meth-oxy-benz-yl)(2-meth-oxy-benzyl-idene)aza-nium (2-meth-oxy-phen-yl)methanaminium tetra-chloridozincate(II) monohydrate.
作者信息
El Glaoui Meher, Jeanneau Erwann, Zeller Matthias, Lefebvre Frederic, Ben Nasr Cherif
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):m791. doi: 10.1107/S1600536810021793.
The title compound, (C(8)H(12)NO)(C(16)H(18)NO(2))[ZnCl(4)]·H(2)O, was obtained as a by-product of the Zn(2+) and HCl catalyzed condensation of (2-meth-oxy-phen-yl)methanamine in water. Both cations feature an intra-molecular N-H⋯O hydrogen bond. In the crystal, the components are linked by an extensive three-dimensional network of N-H⋯O, O-H⋯Cl and N-H⋯Cl hydrogen bonds (three of them bifurcated). Weak C-H⋯O intera-ctions also occur.
标题化合物（C₈H₁₂NO）（C₁₆H₁₈NO₂）[ZnCl₄]·H₂O是在水中Zn²⁺和HCl催化下（2-甲氧基苯基）甲胺缩合反应的副产物。两种阳离子均具有分子内N-H⋯O氢键。在晶体中，各组分通过广泛的N-H⋯O、O-H⋯Cl和N-H⋯Cl氢键三维网络相连（其中三个为分叉氢键）。还存在弱的C-H⋯O相互作用。
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