（E）-4-溴-N'-（4-羟基-3-甲氧基苄叉基）苯甲酰肼一水合物
(E)-4-Bromo-N'-(4-hy-droxy-3-meth-oxy-benzyl-idene)benzohydrazide monohydrate.
作者信息
Horkaew Jirapa, Chantrapromma Suchada, Anantapong Teerasak, Kanjana-Opas Akkharawit, Fun Hoong-Kun
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):o1069-70. doi: 10.1107/S160053681201032X. Epub 2012 Mar 14.
In the title compound, C(15)H(13)BrN(2)O(3)·H(2)O, the dihedral angle between the two benzene rings is 13.92 (6)°. The meth-oxy group of the 4-hy-droxy-3-meth-oxy-phenyl is almost coplanar with its bound benzene ring, as seen by the C(meth-yl)-O-C-C torsion angle of -0.35 (16)°. In the crystal, mol-ecules are linked into a three-dimensional network by N-H⋯O, O-H⋯N and O-H⋯O hydrogen bonds and also weak C-H⋯O inter-actions. A short C⋯O contact of 3.0191 (15) Å is also present.
在标题化合物C₁₅H₁₃BrN₂O₃·H₂O中，两个苯环之间的二面角为13.92 (6)°。4-羟基-3-甲氧基苯基的甲氧基与其相连的苯环几乎共面，由C(甲基)-O-C-C扭转角为-0.35 (16)°可见。在晶体中，分子通过N-H⋯O、O-H⋯N和O-H⋯O氢键以及弱C-H⋯O相互作用连接成三维网络。还存在3.0191 (15) Å的短C⋯O接触。
Zotero 插件