• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

（E）-4-溴-N'-（4-羟基-3-甲氧基苄叉基）苯甲酰肼一水合物

(E)-4-Bromo-N'-(4-hy-droxy-3-meth-oxy-benzyl-idene)benzohydrazide monohydrate.

作者信息

Horkaew Jirapa, Chantrapromma Suchada, Anantapong Teerasak, Kanjana-Opas Akkharawit, Fun Hoong-Kun

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):o1069-70. doi: 10.1107/S160053681201032X. Epub 2012 Mar 14.

DOI:10.1107/S160053681201032X
PMID:22589936
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3344027/
Abstract

In the title compound, C(15)H(13)BrN(2)O(3)·H(2)O, the dihedral angle between the two benzene rings is 13.92 (6)°. The meth-oxy group of the 4-hy-droxy-3-meth-oxy-phenyl is almost coplanar with its bound benzene ring, as seen by the C(meth-yl)-O-C-C torsion angle of -0.35 (16)°. In the crystal, mol-ecules are linked into a three-dimensional network by N-H⋯O, O-H⋯N and O-H⋯O hydrogen bonds and also weak C-H⋯O inter-actions. A short C⋯O contact of 3.0191 (15) Å is also present.

摘要

在标题化合物C₁₅H₁₃BrN₂O₃·H₂O中，两个苯环之间的二面角为13.92 (6)°。4-羟基-3-甲氧基苯基的甲氧基与其相连的苯环几乎共面，由C(甲基)-O-C-C扭转角为-0.35 (16)°可见。在晶体中，分子通过N-H⋯O、O-H⋯N和O-H⋯O氢键以及弱C-H⋯O相互作用连接成三维网络。还存在3.0191 (15) Å的短C⋯O接触。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7d0/3344027/bfdcfe1ee756/e-68-o1069-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7d0/3344027/d1041e03f594/e-68-o1069-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7d0/3344027/bfdcfe1ee756/e-68-o1069-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7d0/3344027/d1041e03f594/e-68-o1069-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7d0/3344027/bfdcfe1ee756/e-68-o1069-fig2.jpg

相似文献

1
(E)-4-Bromo-N'-(4-hy-droxy-3-meth-oxy-benzyl-idene)benzohydrazide monohydrate.（E）-4-溴-N'-（4-羟基-3-甲氧基苄叉基）苯甲酰肼一水合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):o1069-70. doi: 10.1107/S160053681201032X. Epub 2012 Mar 14.
2
(E)-N'-(3-Eth-oxy-4-hy-droxy-benzyl-idene)-4-meth-oxy-benzohydrazide.（E）-N'-（3-乙氧基-4-羟基苯亚甲基）-4-甲氧基苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):o849-50. doi: 10.1107/S1600536812007374. Epub 2012 Feb 24.
3
Crystal structure of ()-4-hy-droxy-'-(3-meth-oxy-benzyl-idene)benzohydrazide.（）-4-羟基-'-（3-甲氧基-亚苄基）苯甲酰肼的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Aug 26;72(Pt 9):1339-1342. doi: 10.1107/S2056989016013268. eCollection 2016 Sep 1.
4
N'-[(E)-5-Bromo-2-hy-droxy-3-meth-oxy-benzyl-idene]-4-meth-oxy-benzohydrazide monohydrate.N'-[(E)-5-溴-2-羟基-3-甲氧基亚苄基]-4-甲氧基苯甲酰肼一水合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Oct 1;68(Pt 10):o2821-2. doi: 10.1107/S1600536812033806. Epub 2012 Sep 1.
5
(E)-N'-(5-Bromo-2-hy-droxy-benzyl-idene)-4-hy-droxy-3-meth-oxy-benzohydrazide methanol solvate.（E）-N'-（5-溴-2-羟基苄叉基）-4-羟基-3-甲氧基苯甲酰肼甲醇溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):o1662. doi: 10.1107/S1600536810022063.
6
(E)-4-Hy-droxy-N'-(3-hy-droxy-4-meth-oxy-benzyl-idene)benzohydrazide.（E）-4-羟基-N'-（3-羟基-4-甲氧基苯亚甲基）苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):o2644-5. doi: 10.1107/S1600536811036579. Epub 2011 Sep 14.
7
(E)-N'-(5-Bromo-2-hy-droxy-3-meth-oxy-benzyl-idene)-2-hy-droxy-benzohydrazide monohydrate.（E）-N'-（5-溴-2-羟基-3-甲氧基苄叉基）-2-羟基苯甲酰肼一水合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2040. doi: 10.1107/S1600536812024816. Epub 2012 Jun 13.
8
(E)-4-Hy-droxy-N'-(2-hy-droxy-4-meth-oxy-benzyl-idene)benzohydrazide.（E）-4-羟基-N'-（2-羟基-4-甲氧基苄叉基）苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2279. doi: 10.1107/S1600536812027201. Epub 2012 Jun 30.
9
(E)-4-Hy-droxy-N'-(4-hy-droxy-3-meth-oxy-benzyl-idene)benzohydrazide.（E）-4-羟基-N'-（4-羟基-3-甲氧基苄叉基）苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 13;66(Pt 12):o3126-7. doi: 10.1107/S1600536810045162.
10
(E)-N'-(5-Bromo-2-hy-droxy-benzyl-idene)-2-meth-oxy-benzohydrazide.（E）-N'-（5-溴-2-羟基-亚苄基）-2-甲氧基-苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):o1658. doi: 10.1107/S1600536810022002.

引用本文的文献

1
Crystal structure, Hirshfeld surface analysis and frontier mol-ecular orbital analysis of ()-4-bromo-'-(2,3-di-chloro-benzyl-idene)benzohydrazide.（）-4-溴-'-（2,3-二氯亚苄基）苯甲酰肼的晶体结构、 Hirshfeld表面分析和前沿分子轨道分析
Acta Crystallogr E Crystallogr Commun. 2019 Feb 5;75(Pt 3):324-327. doi: 10.1107/S2056989019001816. eCollection 2019 Mar 1.
2
4-Dimethyl-amino-N'-(4-nitro-benzyl-idene)benzohydrazide methanol monosolvate.4-二甲基氨基-N'-(4-硝基-亚苄基)苯甲酰肼甲醇单溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Oct 1;68(Pt 10):o2828. doi: 10.1107/S1600536812037063. Epub 2012 Sep 1.
3

本文引用的文献

1
(E)-4-Hy-droxy-N'-(3,4,5-trimeth-oxy-benzyl-idene)benzohydrazide.（E）-4-羟基-N'-（3,4,5-三甲氧基-亚苄基）苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):o2985. doi: 10.1107/S1600536811041535. Epub 2011 Oct 22.
2
(E)-N'-(2,3-Dihy-droxy-benzyl-idene)-4-meth-oxy-benzohydrazide.（E）-N'-（2,3-二羟基苄叉基）-4-甲氧基苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):o3224. doi: 10.1107/S1600536811045740. Epub 2011 Nov 12.
3
(E)-4-Hy-droxy-N'-(3-hy-droxy-4-meth-oxy-benzyl-idene)benzohydrazide.
N'-(3,4-Dihy-droxy-benzyl-idene)-2-meth-oxy-benzohydrazide.
N'-(3,4-二羟基-亚苄基)-2-甲氧基-苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2034. doi: 10.1107/S1600536812025688. Epub 2012 Jun 13.
4
(E)-N'-(4-Eth-oxy-benzyl-idene)-4-hy-droxy-benzohydrazide dihydrate.（E）-N'-（4-乙氧基-亚苄基）-4-羟基-苯甲酰肼二水合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):o1655-6. doi: 10.1107/S1600536812019356. Epub 2012 May 5.
5
N'-(3-Fluoro-benzyl-idene)-4-hy-droxy-3-meth-oxy-benzohydrazide methanol monosolvate.N'-(3-氟-亚苄基)-4-羟基-3-甲氧基-苯甲酰肼甲醇单溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):o1338. doi: 10.1107/S1600536812012196. Epub 2012 Apr 6.
6
(E)-N'-(5-Bromo-2-hy-droxy-benzyl-idene)-4-(dimethyl-amino)-benzohydrazide.（E）-N'-（5-溴-2-羟基-亚苄基）-4-（二甲基氨基）-苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):o1304. doi: 10.1107/S1600536812013785. Epub 2012 Apr 4.
（E）-4-羟基-N'-（3-羟基-4-甲氧基苯亚甲基）苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):o2644-5. doi: 10.1107/S1600536811036579. Epub 2011 Sep 14.
4
Structure validation in chemical crystallography.化学晶体学中的结构验证
Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
5
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
6
Synthesis of some bioactive 2-bromo-5-methoxy-N'-[4-(aryl)-1,3-thiazol-2-yl]benzohydrazide derivatives.一些生物活性2-溴-5-甲氧基-N'-[4-(芳基)-1,3-噻唑-2-基]苯甲酰肼衍生物的合成
Eur J Med Chem. 2007 Mar;42(3):425-9. doi: 10.1016/j.ejmech.2006.09.010. Epub 2006 Oct 30.
7
Synthesis and antifungal activity of cholesterol-hydrazone derivatives.胆固醇腙衍生物的合成及其抗真菌活性
Eur J Med Chem. 2004 Dec;39(12):1067-71. doi: 10.1016/j.ejmech.2004.07.005.