（2-{[1,1-双（羟甲基）-2-氧化乙基]亚氨基甲基}-4-氯苯酚根合-κO，N，O′）二丁基锡（IV）
(2-{[1,1-Bis(hy-droxy-meth-yl)-2-oxidoeth-yl]imino-meth-yl}-4-chloro-phenolato-κO,N,O')dibutyl-tin(IV).
作者信息
Lee See Mun, Mohd Ali Hapipah, Lo Kong Mun
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):m793. doi: 10.1107/S1600536810021872.
Abstract
In the title compound, [Sn(C(4)H(9))(2)(C(11)H(12)BrNO(4))], the Schiff base ligand chelates to the Sn(IV) atom through the two deprotonated hy-droxy groups, as well as through the N atom, to confer an overall cis-C(2)SnNO(2) trigonal-bipyramidal geometry at the Sn(IV) atom [C-Sn-C = 129.92 (9)°]. The remaining methyl-enehy-droxy groups engage in O-H⋯O hydrogen bonding with the O atoms of adjacent mol-ecules, leading to infinite supra-molecular chains propagating in [001].
摘要
在标题化合物[Sn(C₄H₉)₂(C₁₁H₁₂BrNO₄)]中，席夫碱配体通过两个去质子化的羟基以及氮原子与Sn(IV)原子螯合，在Sn(IV)原子处形成一个整体的顺式-C₂SnNO₂三角双锥几何构型[C-Sn-C = 129.92 (9)°]。其余的亚甲基羟基与相邻分子的氧原子形成O-H⋯O氢键，导致在[001]方向上延伸的无限超分子链。
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本文引用的文献
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