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[(1S,2S)-2-(1-{[2-(2-氧化苄基亚氨基)-环己基]亚氨基}-乙基)苯酚根合-κO,N,N',O']铜(II)

[(1S,2S)-2-(1-{[2-(2-Oxidobenzyl-idene-amino)-cyclo-hex-yl]imino}-eth-yl)phenolato-κO,N,N',O']copper(II).

作者信息

Suleiman Gwaram Nura, Khaledi Hamid, Mohd Ali Hapipah

机构信息

Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 18;66(Pt 7):m813. doi: 10.1107/S1600536810022889.

Abstract

In the title compound, [Cu(C(21)H(22)N(2)O(2))], the cyclo-hexyl ring adopts a chair conformation with the two imine groups linked at equatorial positions. The Cu(II) ion is coordinated by two N atoms and two O atoms from the bis-Schiff base ligand in a slightly distorted square-planar geometry. The dihedral angle between the two benzene rings is 45.89 (9)°. The crystal structure is devoid of any classical hydrogen bonds. However, inter-molecular C-H⋯O inter-actions are present and stabilize the structure.

摘要

在标题化合物[Cu(C₂₁H₂₂N₂O₂)]中,环己基环呈椅式构象,两个亚胺基团连接在赤道位置。Cu(II)离子由双席夫碱配体的两个N原子和两个O原子配位,形成略微扭曲的平面正方形几何构型。两个苯环之间的二面角为45.89 (9)°。晶体结构中不存在任何经典氢键。然而,存在分子间C—H⋯O相互作用并使结构稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e7cf/3007062/84942a1b83f6/e-66-0m813-fig1.jpg

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