氯（2-{1-[(2-吗啉代乙基)亚氨基]乙基}苯酚根-κN,N',O）铜（II）
Chlorido(2-{1-[(2-morpholino-eth-yl)imino]-eth-yl}phenolato-κN,N',O)copper(II).
作者信息
Ikmal Hisham Nurul Azimah, Suleiman Gwaram Nura, Khaledi Hamid, Mohd Ali Hapipah
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 11;67(Pt 1):m57. doi: 10.1107/S1600536810051160.
In the title compound, [CuCl(C(14)H(19)N(2)O(2))], the Cu(II) ion is four-coordinated by one deprotonated N,N',O-tridentate Schiff base and one chloride ion in a distorted square-planar geometry. In the crystal, adjacent mol-ecules are linked via C-H⋯Cl and C-H⋯O inter-actions, forming infinite layers parallel to the (100) plane. The structure was determined from a non-merohedrally twined crystal [twin ratio 0.777 (3):0.223 (3)].
在标题化合物[CuCl(C₁₄H₁₉N₂O₂)]中，Cu(II)离子由一个去质子化的N,N',O-三齿席夫碱和一个氯离子以扭曲的平面正方形几何构型四配位。在晶体中，相邻分子通过C—H⋯Cl和C—H⋯O相互作用相连，形成平行于(100)平面的无限层。该结构由一个非镜像孪晶晶体确定[孪晶比率为0.777 (3):0.223 (3)]。
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