双（μ-4-苯基吡啶氮氧化物-κO:O）双[双（1,1,1,5,5,5-六氟戊烷-2,4-二酮）铜（II）]

Bis(μ-4-phenyl-pyridine N-oxide-κO:O)bis-[bis-(1,1,1,5,5,5-hexa-fluoro-pentane-2,4-dionato)copper(II)].

作者信息

Ramos Ana I, Fernandes José A, Silva Patrícia, Ribeiro-Claro Paulo J A, Braga Susana S, Almeida Paz Filipe A

机构信息

Department of Chemistry, CICECO, University of Aveiro, 3810-193 Aveiro, Portugal.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 23;66(Pt 7):m824-5. doi: 10.1107/S1600536810022567.

DOI:10.1107/S1600536810022567

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3006976/

Abstract

The asymmetric unit of the title compound, [Cu(2)(C(5)HF(6)O(2))(4)(C(11)H(9)NO)(2)], contains one half of the centrosymmetric dinuclear complex. The coordination geometry of the Cu(II) atom is octa-hedral, exhibiting a typical Jahn-Teller distortion. One trifluoro-methyl group is rotationally disordered between two orientations in a 1:1 ratio.

摘要

标题化合物[Cu₂(C₅HF₆O₂)₄(C₁₁H₉NO)₂]的不对称单元包含中心对称双核配合物的一半。Cu(II)原子的配位几何形状为八面体，呈现出典型的 Jahn-Teller 畸变。一个三氟甲基在两个取向之间以 1:1 的比例发生旋转无序。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d4e9/3006976/0fa360fc035c/e-66-0m824-fig1.jpg

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

相似文献

1

Bis(μ-4-phenyl-pyridine N-oxide-κO:O)bis-[bis-(1,1,1,5,5,5-hexa-fluoro-pentane-2,4-dionato)copper(II)].双（μ-4-苯基吡啶氮氧化物-κO:O）双[双（1,1,1,5,5,5-六氟戊烷-2,4-二酮）铜（II）]

Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 23;66(Pt 7):m824-5. doi: 10.1107/S1600536810022567.

2

A 2:1 cocrystal of the cis and trans isomers of bis-[1,1,1,5,5,5-hexa-fluoro-pentane-2,4-dionato(1-)-κO,O']bis-(4-phenyl-pyridine N-oxide-κO)copper(II).双-[1,1,1,5,5,5-六氟戊烷-2,4-二酮基(1-)-κO,O']双-(4-苯基吡啶N-氧化物-κO)铜(II)顺式和反式异构体的2:1共晶体。

Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 27;66(Pt 12):m1689-90. doi: 10.1107/S1600536810049196.

3

trans-Bis(1,1,1,5,5,5-hexa-fluoro-pentane-2,4-dionato-κO,O')bis-(4-methyl-1,2,3-selenadiazole-κN)copper(II).反式双（1,1,1,5,5,5-六氟戊烷-2,4-二酮基-κO,O'）双（4-甲基-1,2,3-硒二唑-κN）铜（II）

Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 30;66(Pt 2):m241. doi: 10.1107/S1600536810001297.

4

[4-Bromo-N-(pyridin-2-yl-methyl-idene)aniline-κN,N']bis-(1,1,1,5,5,5-hexa-fluoro-pentane-2,4-dionato-κO,O')nickel(II).[4-溴-N-(吡啶-2-基亚甲基)苯胺-κN,N']双-(1,1,1,5,5,5-六氟戊烷-2,4-二酮-κO,O')镍(II)

Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m404-5. doi: 10.1107/S1600536811005599. Epub 2011 Mar 9.

5

Bis(pentane-2,4-dionato-κO,O')bis-[4,4,5,5-tetra-methyl-2-(4-pyridyl)-imidazoline-1-oxyl 3-oxide-κN]manganese(II).双（2,4-戊二酮-κO,O'）双-[4,4,5,5-四甲基-2-（4-吡啶基）-咪唑啉-1-氧基3-氧化物-κN]锰（II）

Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 26;64(Pt 8):m1077. doi: 10.1107/S1600536808022952.

6

[(4-Bromo-phen-yl)(2-pyridyl-methyl-idene)amine-κN,N']bis-(1,1,1,5,5,5-hexa-fluoro-pentane-2,4-dionato-κO,O')cobalt(II).[(4-溴苯基)(2-吡啶基亚甲基)胺-κN,N']双(1,1,1,5,5,5-六氟戊烷-2,4-二酮-κO,O')钴(II)

Acta Crystallogr Sect E Struct Rep Online. 2010 Aug 21;66(Pt 9):m1138-9. doi: 10.1107/S1600536810032757.

7

Bis[μ-pentane-2,4-dionato(1-)]bis-{aqua-[1,1,1,5,5,5-hexa-fluoro-pentane-2,4-dionato(1-)]cobalt(II)}.双[μ-戊烷-2,4-二酮(1-)]双-{水合-[1,1,1,5,5,5-六氟-戊烷-2,4-二酮(1-)]钴(II)}

Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 31;65(Pt 11):m1476. doi: 10.1107/S1600536809044389.

8

catena-Poly[[tetra-kis(μ(2)-acetato-κO:O')dicopper(II)(Cu-Cu)]-μ(2)-acetato-κO:O'-[bis-[μ(2)-3-(dimethyl-amino)propan-1-olato]-κN,O:O;κO:N,O-bis-[(tetra-hydro-furan-κO)copper(II)]]-μ(2)-acetato-κO:O'].链状聚[[四-双(μ(2)-乙酸根-κO:O')二铜(II)(铜-铜)]-μ(2)-乙酸根-κO:O'-[双-[μ(2)-3-(二甲基氨基)丙醇根]-κN,O:O;κO:N,O-双-[(四氢呋喃-κO)铜(II)]]-μ(2)-乙酸根-κO:O']

Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 9;64(Pt 9):m1139-40. doi: 10.1107/S1600536808024148.

9

Bis(pentane-2,4-dionato)bis-[2-(4-pyrid-yl)-4,4,5,5-tetra-methyl-imidazoline-1-oxyl 3-oxide]nickel(II).双（戊烷 - 2,4 - 二酮）双 - [2 - （4 - 吡啶基） - 4,4,5,5 - 四甲基 - 咪唑啉 - 1 - 氧基3 - 氧化物]镍（II）

Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 25;64(Pt 7):m957. doi: 10.1107/S1600536808018552.

10

Bis(pyridine-κN)bis-[4,4,4-trifluoro-1-(4-fluoro-phen-yl)butane-1,3-dionato-κO,O']cobalt(II).双（吡啶-κN）双-[4,4,4-三氟-1-（4-氟苯基）丁烷-1,3-二酮-κO,O']钴（II）

Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 16;64(Pt 2):m347. doi: 10.1107/S1600536807067955.

引用本文的文献

1

A 2:1 cocrystal of the cis and trans isomers of bis-[1,1,1,5,5,5-hexa-fluoro-pentane-2,4-dionato(1-)-κO,O']bis-(4-phenyl-pyridine N-oxide-κO)copper(II).双-[1,1,1,5,5,5-六氟戊烷-2,4-二酮基(1-)-κO,O']双-(4-苯基吡啶N-氧化物-κO)铜(II)顺式和反式异构体的2:1共晶体。

Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 27;66(Pt 12):m1689-90. doi: 10.1107/S1600536810049196.

本文引用的文献

1

Diaqua-bis(ethyl-enediamine-κN,N')copper(II) bis-(4-phenyl-benzoate) 2.66-hydrate.二水合双（乙二胺-κN,N'）铜（II）双（4-苯基苯甲酸酯）2.66水合物

Acta Crystallogr Sect E Struct Rep Online. 2010 May 8;66(Pt 6):m626-7. doi: 10.1107/S1600536810016223.

2

An element of surprise--efficient copper-functionalized dye-sensitized solar cells.惊喜元素——高效铜功能化染料敏化太阳能电池。

Chem Commun (Camb). 2008 Aug 28(32):3717-9. doi: 10.1039/b808491b. Epub 2008 Jul 8.

3

A short history of SHELX.SHELX简史。

Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.

4

A novel microporous copper silicate: Na2Cu2Si4O11.2H2O.

Chem Commun (Camb). 2005 Jan 14(2):171-3. doi: 10.1039/b410731d. Epub 2004 Nov 18.

5

The Cambridge Structural Database: a quarter of a million crystal structures and rising.剑桥结构数据库：拥有二十五万个晶体结构且数量不断增加。

Acta Crystallogr B. 2002 Jun;58(Pt 3 Pt 1):380-8. doi: 10.1107/s0108768102003890. Epub 2002 May 29.