聚[（μ(3)-4-氨基苯磺酸根-κN:O:O）（三苯基膦-κP）银（I）]
Poly[(μ(3)-4-amino-benzene-sulfonato-κN:O:O)(triphenyl-phosphine-κP)silver(I)].
作者信息
Sadeghi Omid, Amini Mostafa M, Ng Seik Weng
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 26;66(Pt 7):m855-6. doi: 10.1107/S1600536810024207.
In the title 1:1 silver 4-amino-benzene-sulfonate adduct with triphenyl-phosphine, Ag(C(6)H(6)NO(3)S)(C(18)H(15)P), the sulfon-ate -SO(3) unit bridges, through only one O atom, two phosphine-coordinated Ag atoms, forming a centrosymmetric Ag(2)O(2) rhombus. The Ag(+) cation adopts a considerably distorted a tetra-hedral coordination. In the crystal, adjacent binuclear mol-ecules are connected into a layer motif through the amino group of the anion; the layers are perpendicular to the a axis.
在标题化合物1:1的4-氨基苯磺酸银与三苯基膦加合物[Ag(C₆H₆NO₃S)(C₁₈H₁₅P)]ₙ中，磺酸根-SO₃单元仅通过一个O原子桥连两个与膦配位的Ag原子，形成一个中心对称的Ag₂O₂菱形。Ag⁺阳离子采用严重扭曲的四面体配位。在晶体中，相邻的双核分子通过阴离子的氨基连接成层状结构；这些层垂直于a轴。
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