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链状聚[[[四水合锌（II）]-μ-4,4'-联吡啶-κN:N']苯-1,4-二羧酸酯]

catena-Poly[[[tetra-aqua-zinc(II)]-μ-4,4'-bipyridine-κN:N'] benzene-1,4-di-carboxyl-ate].

作者信息

Ruan Ming-Bo, Deng Jian-Cheng, Li Zhi-Gang, Xu Jing-Wei

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 6;65(Pt 7):m743. doi: 10.1107/S1600536809019412.

DOI:10.1107/S1600536809019412
PMID:21582682
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969229/
Abstract

In the title compound, {Zn(C(10)H(8)N(2))(H(2)O)(4)}(n), the Zn(II) atoms, lying on a twofold rotation axis, are bridged by 4,4'-bipyridine ligands, resulting in a linear chain along the b axis. In the chain, the Zn(II) atom adopts a slightly distorted octa-hedral coordination geometry involving four water mol-ecules at the equatorial positions. The noncoordinated benzene-1,4-dicarboxyl-ate anion, which is also located on a twofold rotation axis, bridges adjacent chains through O-H⋯O hydrogen bonds, forming a three-dimensional supra-molecular network.

摘要

在标题化合物{Zn(C₁₀H₈N₂)(H₂O)₄}ₙ中，位于二重旋转轴上的Zn(II)原子由4,4'-联吡啶配体桥连，形成沿b轴的线性链。在该链中，Zn(II)原子采用略微扭曲的八面体配位几何构型，赤道位置有四个水分子。未配位的苯-1,4-二羧酸根阴离子也位于二重旋转轴上，通过O-H⋯O氢键桥连相邻链，形成三维超分子网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/88df/2969229/5f02e7aebb87/e-65-0m743-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/88df/2969229/7ab6443aedb5/e-65-0m743-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/88df/2969229/5f02e7aebb87/e-65-0m743-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/88df/2969229/7ab6443aedb5/e-65-0m743-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/88df/2969229/5f02e7aebb87/e-65-0m743-fig2.jpg

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