（乙酸根 - κO,O'）双（1,10 - 菲咯啉 - κN,N'）铜（II）三氟乙酸酯四水合物
(Acetato-κO,O')bis-(1,10-phenanthroline-κN,N')copper(II) trifluoro-acetate tetra-hydrate.
作者信息
Wang Jinxia, Jin Zhuping
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 30;66(Pt 7):m865. doi: 10.1107/S1600536810024359.
In the title compound, Cu(CH(3)CO(2))(C(12)H(8)N(2))(2)·4H(2)O, the Cu(II) atom shows a distorted octa-hedral coordination with four N atoms [Cu-N = 2.015 (3)-2.244 (3) Å] from the two phenanthroline ligands and two O atoms from the acetate [Cu-O = 1.953 (3) and 2.764 (3) Å]. Strong inter-molecular O-H⋯O hydrogen-bonding inter-actions consolidate the crystal packing. The F atoms of the anion are disordered over two positions in a 0.5233 (3):0.4767 (3) ratio.
在标题化合物Cu(CH₃CO₂)(C₁₂H₈N₂)₂·4H₂O中，Cu(II)原子呈现出扭曲的八面体配位，与来自两个菲咯啉配体的四个N原子[Cu-N = 2.015(3) - 2.244(3) Å]以及来自乙酸根的两个O原子[Cu-O = 1.953(3)和2.764(3) Å]配位。强烈的分子间O-H⋯O氢键相互作用巩固了晶体堆积。阴离子的F原子在两个位置上无序排列，比例为0.5233(3):0.4767(3)。
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