二水合双（乙酸根-κO）[1,2-双（2-吡啶基甲氧基）苯-κN,O,O',N']铜（II）
Bis(acetato-κO)[1,2-bis-(2-pyridyl-meth-oxy)benzene-κN,O,O',N']copper(II) tetra-hydrate.
作者信息
Zhang Shuang, Wang Yu-Jie, Ma Dong-Sheng, Liu Ying, Gao Jin-Sheng
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):m787. doi: 10.1107/S1600536810021495.
Abstract
In the title compound, [Cu(CH(3)COO)(2)(C(18)H(16)N(2)O(2))]·4H(2)O, the Cu(II) ion is six-coordinated in a Jahn-Teller-distorted octa-hedral geometry environment defined by four O atoms and two N atoms. A chain structure along [100] is built up by inter-molecular O-H⋯O hydrogen bonds involving the uncoordinated water mol-ecules.
摘要
在标题化合物[Cu(CH₃COO)₂(C₁₈H₁₆N₂O₂)]·4H₂O中，Cu(II)离子在由四个O原子和两个N原子定义的 Jahn-Teller 畸变八面体几何环境中呈六配位。沿着[100]方向形成了一个链状结构，该结构由涉及未配位水分子的分子间 O—H⋯O 氢键构成。
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