Durka Maxime, Norberg Bernadette, Roué Yvain, Vincent Stéphane P, Wouters Johan
Department of Chemistry, University of Namur, 61 Rue de Bruxelles, B-5000 Namur, Belgium.
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 5;66(Pt 7):o1525. doi: 10.1107/S1600536810019604.
In the title compound, C(33)H(34)O(5)S·H(2)O, the mannopyran-oside ring adopts a chair conformation with the 2-α-thio-phenyl group occupying an axial position. One of the pendant benzyl groups is disordered over two sets of sites in a 0.5:0.5 ratio. In the crystal, the water mol-ecule makes two O-H⋯O hydrogen bonds to an adjacent sugar mol-ecule with the O atoms of the primary alcohol and ether groups acting as acceptors. At the same time, the OH group of the sugar makes a hydrogen bond to a water mol-ecule.
在标题化合物C(33)H(34)O(5)S·H(2)O中，甘露吡喃糖苷环呈椅式构象，2-α-硫代苯基处于轴向位置。一个侧链苄基在两组位置上无序排列，比例为0.5:0.5。在晶体中，水分子与相邻的糖分子形成两个O-H⋯O氢键，伯醇基团和醚基团的O原子作为受体。同时，糖的OH基团与一个水分子形成氢键。
