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9-(4-羟基-3-甲氧基苯基)-3,3,6,6-四甲基-3,4,5,6-四氢-9H-占吨-1,8(2H,7H)-二酮

9-(4-Hy-droxy-3-meth-oxy-phen-yl)-3,3,6,6-tetra-methyl-3,4,5,6-tetra-hydro-9H-xanthene-1,8(2H,7H)-dione.

作者信息

Hasanudin Noorhafizah, Abdul Rahim Aisyah Saad, Mohamed Nornisah, Quah Ching Kheng, Fun Hoong-Kun

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 5;66(Pt 7):o1538-9. doi: 10.1107/S1600536810020258.

Abstract

In the title compound, C(24)H(28)O(5), the two cyclo-hexene rings adopt envelope conformations, and the planes through the coplanar atoms makes dihedral angles of 82.86 (6) and 77.90 (6)° with the benzene ring. The two cyclo-hexene rings make a dihedral angle of 5.33 (6)° between their least-squares planes. The pyran ring adopts a flattened boat conformation. In the crystal packing, mol-ecules are linked into two-dimensional networks parallel to the ab plane via O-H⋯O and C-H⋯O inter-actions.

摘要

在标题化合物C₂₄H₂₈O₅中,两个环己烯环呈信封式构象,通过共面原子的平面与苯环的二面角分别为82.86 (6)°和77.90 (6)°。两个环己烯环的最小二乘平面之间的二面角为5.33 (6)°。吡喃环呈扁平船式构象。在晶体堆积中,分子通过O—H⋯O和C—H⋯O相互作用连接成平行于ab平面的二维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6826/3007007/4553330ac689/e-66-o1538-fig1.jpg

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