Sureshbabu N, Sughanya V
Department of Chemistry, Annamalai University, Annamalai Nagar 608 002, Tamil Nadu, India.
Acta Crystallogr E Crystallogr Commun. 2015 Aug 26;71(Pt 9):o688-9. doi: 10.1107/S2056989015014966. eCollection 2015 Sep 1.
In the acridinedione moiety of the title compound, C32H37NO4, the central di-hydro-pyridine ring adopts a flattened-boat conformation, with the N atom and the methine C atom displaced from the mean plane of the other four atoms by 0.0513 (14) and 0.1828 (18) Å, respectively. The two cyclo-hexenone rings adopt envelope conformations, with the tetra-subsituted C atoms as the flap atoms. The 3,4-di-meth-oxy--benzene and benzyl rings are almost normal to the di-hydro-pyridine mean plane, with dihedral angles of 89.47 (9) and 82.90 (11)°, respectively. In the crystal, mol-ecules are linked via a pair of C-H⋯O hydrogen bonds, forming inversion dimers, which are, in turn, linked by C-H⋯O hydrogen bonds, forming slabs lying parallel to (001).
在标题化合物C32H37NO4的吖啶二酮部分中,中心二氢吡啶环呈扁平船式构象,N原子和次甲基C原子分别偏离其他四个原子的平均平面0.0513(14)和0.1828(18)Å。两个环己烯酮环呈信封式构象,以四取代的C原子作为瓣原子。3,4-二甲氧基苯环和苄基环几乎垂直于二氢吡啶平均平面,二面角分别为89.47(9)和82.90(11)°。在晶体中,分子通过一对C-H⋯O氢键相连,形成反演二聚体,这些二聚体又通过C-H⋯O氢键相连,形成平行于(001)的片层。