Pervez Humayun, Ahmad Maqbool, Yaqub Muhammad, Tahir M Nawaz, Saira Naveeda
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 23;66(Pt 7):o1729. doi: 10.1107/S1600536810023263.
The title compound, C(18)H(18)N(2)O(3), is the product of the heterocyclic ring cleavage at position 2 of 1-propionylisatin. Two centrosymmetric cyclic motifs, viz. R(2) (2)(14) and R(2) (2)(18), are formed by N-H⋯O hydrogen bonds with the propanamide and amino-phenyl units, respectively, as the N-H donors. These motifs combine into two C(2) (2)(8) chain motifs parallel to the b axis. The chain structure is stabilized by C-H⋯π inter-actions between the benzene rings, where C-H is from the phenyl ring of the cleaved part of 1-pro-pionylisatin.
标题化合物C(18)H(18)N(2)O(3)是1-丙酰异吲哚酮在2位的杂环开环产物。分别以丙酰胺和氨基苯基单元作为N-H供体,通过N-H⋯O氢键形成了两个中心对称的环状基序,即R(2) (2)(14)和R(2) (2)(18)。这些基序组合成两个平行于b轴的C(2) (2)(8)链状基序。链状结构通过苯环之间的C-H⋯π相互作用得以稳定,其中C-H来自1-丙酰异吲哚酮裂解部分的苯环。