（7E）-5-苄基-7-（2-氯-亚苄基）-3-（2-氯-苯基）-2-苯基-3,3a,4,5,6,7-六氢-2H-吡唑并-[4,3-c]吡啶
(7E)-5-Benzyl-7-(2-chloro-benzyl-idene)-3-(2-chloro-phen-yl)-2-phenyl-3,3a,4,5,6,7-hexa-hydro-2H-pyrazolo-[4,3-c]pyridine.
作者信息
Karthikeyan N S, Mahesh B Uma, Sathiyanarayanan K, Raghavaiah P, Rathore R S
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 23;66(Pt 7):o1734. doi: 10.1107/S1600536810023317.
In the title 2H-pyrazolo-[4,3-c]pyridine derivative, C(32)H(27)Cl(2)N(3), the dihydro-pyrazole ring adopts an envelope conformation and the piperidine fused ring a twisted-chair conformation. Two short intra-molecular C-H⋯Cl contacts are observed. The crystal packing is characterized by dimeric C-Cl⋯π inter-actions involving the 5-benzyl ring, with Cl⋯centroid and closest atomic Cl⋯π distances of 3.778 (2) and 3.366 (4) Å, respectively.
在标题为2H-吡唑并-[4,3-c]吡啶衍生物C(32)H(27)Cl(2)N(3)中，二氢吡唑环呈信封式构象，哌啶稠合环呈扭船式构象。观察到两个短的分子内C-H⋯Cl接触。晶体堆积的特征是涉及5-苄基环的二聚体C-Cl⋯π相互作用，Cl⋯质心和最近原子Cl⋯π距离分别为3.778 (2)和3.366 (4) Å。
Zotero 插件