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5''-(2,4-二氯亚苄基)-1'-(2,4-二氯苯基)-1''-甲基-1',2',3',5',6',7',8',8a'-八氢-二螺-[苊烯-1,3'-中氮茚-2',3''-哌啶]-2,4''(1H)-二酮

5''-(2,4-Dichloro-benzyl-idene)-1'-(2,4-dichloro-phen-yl)-1''-methyl-1',2',3',5',6',7',8',8a'-octa-hydro-dispiro-[acenaphthyl-ene-1,3'-indolizine-2',3''-piperidine]-2,4''(1H)-dione.

作者信息

Suresh J, Vishnupriya R, Kumar R Ranjith, Sivakumar S, Lakshman P L Nilantha

机构信息

Department of Physics, The Madura College, Madurai 625 011, India.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Oct 1;68(Pt 10):o2906. doi: 10.1107/S1600536812037956. Epub 2012 Sep 8.

DOI:10.1107/S1600536812037956
PMID:23125699
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3470255/
Abstract

In the title compound, C(37)H(30)Cl(4)N(2)O(2), the pyridinone ring adopts a twisted half-chair conformation. In the octa-hydro-indolizine fused-ring system, the piperidine ring is in a chair conformation and the pyrrole ring is twisted about the C-N bond linking the five- and six-membered rings. The mol-ecular structure features an intra-molecular C-H⋯O inter-action and the crystal packing is stabilized by C-H⋯π inter-actions.

摘要

在标题化合物C(37)H(30)Cl(4)N(2)O(2)中，吡啶酮环呈扭曲的半椅式构象。在八氢吲哚嗪稠环体系中，哌啶环呈椅式构象，吡咯环围绕连接五元环和六元环的C-N键扭曲。分子结构具有分子内C-H⋯O相互作用，晶体堆积通过C-H⋯π相互作用得以稳定。

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