1-（2-苯基-乙基）金刚烷
1-(2-Phenyl-eth-yl)adamantane.
作者信息
Rouchal Michal, Nečas Marek, Vícha Robert
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 23;66(Pt 7):o1736. doi: 10.1107/S1600536810023251.
Abstract
In the title compound, C(18)H(24), the adamantane cage consists of three fused cyclo-hexane rings in almost ideal chair conformations, with C-C-C angles in the range 108.0 (14)-111.1 (15)°. The phenyl and 1-adamantyl substituents adopt anti orientations with a C-C-C-C torsion angle of 177.10 (16)°. In the crystal packing, the mol-ecules are linked by weak C-H⋯π inter-actions into chains along the a axis.
摘要
在标题化合物C₁₈H₂₄中，金刚烷笼由三个几乎呈理想椅式构象的稠合环己烷环组成，C-C-C键角在108.0(14)°至111.1(15)°范围内。苯基和1-金刚烷基取代基呈反式取向，C-C-C-C扭转角为177.10(16)°。在晶体堆积中，分子通过弱的C-H⋯π相互作用沿a轴连接成链。
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