• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

2-（金刚烷-1-基）-1,3-双-（4-甲基苯基）丙-2-醇

2-(Adamantan-1-yl)-1,3-bis-(4-methyl-phen-yl)propan-2-ol.

作者信息

Babjaková Eva, Bartoš Peter, Vícha Robert

机构信息

Department of Chemistry, Faculty of Technology, Tomas Bata University in Zlin, Nám. T. G. Masaryka 275, Zlín, 762 72, Czech Republic.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Jan 1;69(Pt 1):o108. doi: 10.1107/S1600536812050647. Epub 2012 Dec 19.

DOI:10.1107/S1600536812050647
PMID:23476370
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3588353/
Abstract

The conformation of the title compound, C27H34O, is stabilized by a weak intra-molecular C-H⋯π inter-action. The dihedral angle between the benzene rings is 54.79 (4)°. The adamantane cage consists of three fused cyclo-hexane rings in classical chair conformations, with C-C-C angles in the range 107.75 (10)-111.35 (9)°. Although the mol-ecule contains a hy-droxy group as a conceivable hydrogen-bond donor, this group is sterically hindered by bulky substituents and no hydrogen bonds are observed in the crystal structure.

摘要

标题化合物C27H34O的构象通过弱分子内C-H⋯π相互作用得以稳定。苯环之间的二面角为54.79 (4)°。金刚烷笼由三个呈经典椅式构象的稠合环己烷环组成，C-C-C角在107.75 (10)-111.35 (9)°范围内。尽管该分子含有一个羟基作为潜在的氢键供体，但该基团受到庞大取代基的空间位阻，在晶体结构中未观察到氢键。

相似文献

1
2-(Adamantan-1-yl)-1,3-bis-(4-methyl-phen-yl)propan-2-ol.2-（金刚烷-1-基）-1,3-双-（4-甲基苯基）丙-2-醇
Acta Crystallogr Sect E Struct Rep Online. 2013 Jan 1;69(Pt 1):o108. doi: 10.1107/S1600536812050647. Epub 2012 Dec 19.
2
2-(1-Adamant-yl)-1,3-diphenyl-propan-2-ol.
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 31;66(Pt 8):o2175. doi: 10.1107/S1600536810030047.
3
5-[(E)-2-Fluoro-benzyl-idene]-8-(2-fluoro-phen-yl)-2-hy-droxy-10-methyl-3,10-di-aza-hexa-cyclo-[10.7.1.1.0.0.0]henicosa-1(20),12,14,16,18-pentaen-6-one.5-[(E)-2-氟-亚苄基]-8-(2-氟-苯基)-2-羟基-10-甲基-3,10-二氮杂-六环-[10.7.1.1.0.0.0]二十一碳-1(20),12,14,16,18-五烯-6-酮
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 24;67(Pt 1):o211-2. doi: 10.1107/S1600536810052815.
4
Methyl (2Z)-2-({N-[2-(hy-droxy-meth-yl)phen-yl]-4-methyl-benzene-sulfonamido}-meth-yl)-3-phenyl-prop-2-enoate.（2Z）-2-({N-[2-(羟甲基)苯基]-4-甲基苯磺酰胺基}甲基)-3-苯基-2-丙烯酸甲酯
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):o418-9. doi: 10.1107/S1600536812000864. Epub 2012 Jan 14.
5
[2,6-Bis(biphenyl-4-yl)-4-hy-droxy-4-(pyridin-2-yl)cyclo-hexane-1,3-di-yl]bis-[(pyridin-2-yl)methanone]-butan-2-one (1/1).[2,6-双（联苯-4-基）-4-羟基-4-（吡啶-2-基）环己烷-1,3-二亚基]双[（吡啶-2-基）甲酮]-丁-2-酮（1/1）
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):o1633-4. doi: 10.1107/S1600536812019241. Epub 2012 May 5.
6
2-Hy-droxy-16-[(E)-4-methyl-benzyl-idene]-13-(4-methyl-phen-yl)-12-phenyl-1,11-diaza-penta-cyclo-[12.3.1.0.0.0]octa-deca-3(8),4,6-triene-9,15-dione.2-羟基-16-[(E)-4-甲基亚苄基]-13-(4-甲基苯基)-12-苯基-1,11-二氮杂五环-[12.3.1.0.0.0]十八碳-3(8),4,6-三烯-9,15-二酮
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 24;66(Pt 8):o2086-7. doi: 10.1107/S1600536810028357.
7
3-(4-Chloro-benzo-yl)-4-(4-chloro-phen-yl)-1-phenethyl-piperidin-4-ol.3-（4-氯-苯甲酰基）-4-（4-氯-苯基）-1-苯乙基-哌啶-4-醇
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):o1447-8. doi: 10.1107/S1600536811018034. Epub 2011 May 20.
8
(1-Adamant-yl)diphenyl-methano-l.
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):o1626. doi: 10.1107/S1600536810021707.
9
(1-Adamant-yl)(4-amino-phen-yl)methanol.（1-金刚烷基）（4-氨基苯基）甲醇
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 10;65(Pt 5):o1018. doi: 10.1107/S1600536809012987.
10
2-[6-(4-Bromo-phen-yl)imidazo[2,1-b][1,3]thia-zol-3-yl]-N-[8-(4-hy-droxy-phen-yl)-2-methyl-3-oxo-1-thia-4-aza-spiro-[4.5]decan-4-yl]acetamide ethanol disolvate.2-[6-(4-溴苯基)咪唑并[2,1-b][1,3]噻唑-3-基]-N-[8-(4-羟基苯基)-2-甲基-3-氧代-1-硫杂-4-氮杂螺[4.5]癸烷-4-基]乙酰胺乙醇溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):o1505-6. doi: 10.1107/S1600536812015371. Epub 2012 Apr 21.

本文引用的文献

1
2-(1-Adamant-yl)-1,3-diphenyl-propan-2-ol.
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 31;66(Pt 8):o2175. doi: 10.1107/S1600536810030047.
2
(1-Adamant-yl)diphenyl-methano-l.
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):o1626. doi: 10.1107/S1600536810021707.
3
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.