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4,5-二甲基-2-苯基-1-(对甲苯基)-1H-咪唑

4,5-Dimethyl-2-phenyl-1-(p-tol-yl)-1H-imidazole.

作者信息

Gayathri P, Thiruvalluvar A, Srinivasan N, Jayabharathi J, Butcher R J

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 20;66(Pt 11):o2826. doi: 10.1107/S1600536810040535.

DOI:10.1107/S1600536810040535
PMID:21589013
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3009043/
Abstract

In the title compound, C(18)H(18)N(2), the imidazole ring is essentially planar [maximum deviation = 0.004 (1) Å] and makes dihedral angles of 68.91 (8) and 20.43 (9)° with the tolyl and phenyl rings, respectively. The dihedral angle between the latter rings is 73.62 (8)°. The crystal packing is stabilized by inter-molecular C-H⋯N hydrogen bonds.

摘要

在标题化合物C(18)H(18)N(2)中，咪唑环基本呈平面状[最大偏差 = 0.004 (1) Å]，与甲苯基环和苯基环的二面角分别为68.91 (8)°和20.43 (9)°。后两个环之间的二面角为73.62 (8)°。晶体堆积通过分子间的C—H⋯N氢键得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13ba/3009043/129fef641fe0/e-66-o2826-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13ba/3009043/e32dd162732e/e-66-o2826-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13ba/3009043/129fef641fe0/e-66-o2826-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13ba/3009043/e32dd162732e/e-66-o2826-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13ba/3009043/129fef641fe0/e-66-o2826-fig2.jpg

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