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N-(5-氯-2-甲氧基苯基)苯磺酰胺

N-(5-Chloro-2-meth-oxy-phen-yl)benzene-sulfonamide.

作者信息

Akkurt Mehmet, Abbasi Muhammad Athar, Khan Islam Ullah

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 20;66(Pt 11):o2855. doi: 10.1107/S1600536810041206.

DOI:10.1107/S1600536810041206
PMID:21589040
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3009279/
Abstract

In the title compound, C(13)H(12)ClNO(3)S, the dihedral angle between the two aromatic rings is 73.94 (9)°. An intra-molecular C-H⋯O hydrogen bond occurs. In the crystal, inter-molecular N-H⋯O hydrogen bonds connect the mol-ecules to centrosymmetric dimers, forming an R(2) (2)(8) ring motif. The packing is consolidated by C-H⋯O hydrogen bonds and weak π-π inter-actions [centroid-centroid distances = 3.81 (3) and 3.81 (3) Å].

摘要

在标题化合物C₁₃H₁₂ClNO₃S中,两个芳香环之间的二面角为73.94(9)°。存在分子内C—H⋯O氢键。在晶体中,分子间N—H⋯O氢键将分子连接成中心对称的二聚体,形成R₂²(8)环 motif。堆积通过C—H⋯O氢键和弱的π-π相互作用[质心-质心距离 = 3.81(3)和3.81(3)Å]得以巩固。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7497/3009279/b19f4c49b77c/e-66-o2855-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7497/3009279/8a2cab271dc1/e-66-o2855-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7497/3009279/b19f4c49b77c/e-66-o2855-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7497/3009279/8a2cab271dc1/e-66-o2855-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7497/3009279/b19f4c49b77c/e-66-o2855-fig2.jpg

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