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N-{4-[(3-甲基-苯基)氨磺酰基]苯基}苯甲酰胺

N-{4-[(3-Methyl-phen-yl)sulfamo-yl]phen-yl}benzamide.

作者信息

Lahtinen Manu, Damodara Jyothi, Upadhyaya Poornima, Kolehmainen Erkki

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):o2866. doi: 10.1107/S1600536811040384. Epub 2011 Oct 8.

Abstract

In the title compound, C(20)H(18)N(2)O(3)S, the dihedral angle between the central benzene ring and the amide group is 24.1 (3)° and that between this ring and the aromatic ring of the tolyl group is 68.2 (16)°. In the crystal, adjacent mol-ecules are linked by N-H⋯O hydrogen bonds into a linear chain running along [100]. Weak C-H⋯O contacts also occur. Extensive weak π-π inter-actions exist from both face-to-face and face-to-edge inter-actions occur between the aromatic rings [centroid-centroid distances = 3.612 (2) and 4.843 (2) Å].

摘要

在标题化合物C₂₀H₁₈N₂O₃S中,中心苯环与酰胺基团之间的二面角为24.1(3)°,该环与甲苯基的芳环之间的二面角为68.2(16)°。在晶体中,相邻分子通过N-H⋯O氢键连接成沿[100]方向延伸的线性链。还存在弱的C-H⋯O接触。芳环之间存在广泛的弱π-π相互作用,包括面对面和边对面相互作用[质心-质心距离 = 3.612(2)和4.843(2)Å]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/95d1/3247601/e56650d6c7ed/e-67-o2866-fig1.jpg

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