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Bis(4-cyano-phenolato)[hydro-tris-(3,5-dimethyl-pyrazol-yl)borato]nitro-syl-molybdenum(II)-4-hydroxy-benzonitrile-dichloro-methane (1/1/1).

作者信息

Kassim Mohammad B, McCleverty Jon A

机构信息

School of Chemistry, University of Bristol, Cantock Close, BS8 ITS Bristol, England.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 10;66(Pt 12):m1541-2. doi: 10.1107/S160053681004537X.

DOI:10.1107/S160053681004537X
PMID:21589237
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3011797/
Abstract

In the title compound, [Mo(C(15)H(22)BN(6))(C(7)H(4)NO)(2)(NO)]·C(7)H(5)NO·CH(2)Cl(2), the central Mo(II) atom adopts a distorted cis-MoO(2)N(4) octa-hedral geometry with the hydro-tris-(3,5-dimethyl-pyrazolylborate) anion attached to the metal in an N,N',N''-tridentate tripodal coordination mode. Two O-bonded 4-cyano-phenolate anions and a nitrosyl cation complete the coodination of the Mo(II) atom. Two intra-molecular C-H⋯O and one C-H⋯N hydrogen bonds help to establish the configuration of the complex mol-ecule. The crystal structure is stabilized by inter-molecular C-H⋯N and C-H⋯O hydrogen bonds.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a5db/3011797/d1157d9843ae/e-66-m1541-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a5db/3011797/03a77ae40de5/e-66-m1541-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a5db/3011797/d874c6768613/e-66-m1541-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a5db/3011797/d1157d9843ae/e-66-m1541-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a5db/3011797/03a77ae40de5/e-66-m1541-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a5db/3011797/d874c6768613/e-66-m1541-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a5db/3011797/d1157d9843ae/e-66-m1541-fig3.jpg

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引用本文的文献

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(4-tert-Butyl-pyridine)-chlorido[hydro-tris-(3,5-dimethyl-pyrazol-1-yl)borato]nitro-sylmolybdenum(I) dichloro-methane monosolvate.（4-叔丁基吡啶）氯代[氢三（3,5-二甲基吡唑-1-基）硼酸盐]亚硝酰钼（I）二氯甲烷单溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 30;66(Pt 12):m1696-7. doi: 10.1107/S1600536810048233.

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