（4-叔丁基吡啶）氯代[氢三（3,5-二甲基吡唑-1-基）硼酸盐]亚硝酰钼（I）二氯甲烷单溶剂合物
(4-tert-Butyl-pyridine)-chlorido[hydro-tris-(3,5-dimethyl-pyrazol-1-yl)borato]nitro-sylmolybdenum(I) dichloro-methane monosolvate.
作者信息
Kassim Mohammad B, McCleverty Jon A
机构信息
School of Chemistry, University of Bristol, Cantock Close, BS8 ITS Bristol, England.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 30;66(Pt 12):m1696-7. doi: 10.1107/S1600536810048233.
In the title compound, [Mo(C(15)H(22)BN(6))Cl(NO)(C(9)H(13)N)]·CH(2)Cl(2), the Mo(I) atom adopts a distorted MoClN(5) octa-hedral geometry with the hydro-tris-(3,5-dimethyl-pyrazol-yl)borate anion in an N,N',N''-tridentate tripodal (facial) coordination mode. A 4-tert-butyl-pyrine ligand, chloride anion and a nitrosyl cation complement the coodination of the Mo(I) atom and an intra-molecular C-H⋯Cl hydrogen bond helps to stabilize the configuration of the complex mol-ecule. The packing is stabilized by an inter-molecular C-H⋯Cl hydrogen bond involving the complex mol-ecule and the CH(2)Cl(2) solvent mol-ecule.
在标题化合物[Mo(C₁₅H₂₂BN₆)Cl(NO)(C₉H₁₃N)]·CH₂Cl₂中，Mo(I)原子采取扭曲的MoClN₅八面体几何构型，氢三(3,5-二甲基吡唑基)硼酸根阴离子以N,N',N''-三齿三脚架（面式）配位模式存在。一个4-叔丁基吡啶配体、氯离子阴离子和一个亚硝酰阳离子补充了Mo(I)原子的配位，分子内C-H⋯Cl氢键有助于稳定配合物分子的构型。堆积通过涉及配合物分子和CH₂Cl₂溶剂分子的分子间C-H⋯Cl氢键得以稳定。
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