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{2,2'-[4-氯-5-甲基-邻亚苯基双（亚氨次甲基）]二酚根合}镍（II）

{2,2'-[4-Chloro-5-methyl-o-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato}nickel(II).

作者信息

Wang Haixia

机构信息

Department of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453007, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 13;66(Pt 12):m1571. doi: 10.1107/S1600536810046088.

DOI:10.1107/S1600536810046088
PMID:21589258
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3011529/
Abstract

In the title complex, [Ni(C(21)H(15)ClN(2)O(2))], the Ni(II) ion is coordinated by two N and two O atoms from the tetra-dentate Schiff base ligand in a distorted square geometry. The crystal packing exhibits short inter-molecular Ni⋯Ni distances of 3.273 (3) Å.

摘要

在标题配合物[Ni(C₂₁H₁₅ClN₂O₂)]中，Ni(II)离子由四齿席夫碱配体中的两个N原子和两个O原子配位，呈扭曲的正方形几何构型。晶体堆积显示出分子间Ni⋯Ni的短距离为3.273(3) Å。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/be0e/3011529/ce099d1b5042/e-66-m1571-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/be0e/3011529/ce099d1b5042/e-66-m1571-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/be0e/3011529/ce099d1b5042/e-66-m1571-fig1.jpg

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