Wang Jian-Qiang, Du Ren-Jun, Wang Wei, Luan Chang-Jun, Guo Cheng
Department of Applied Chemistry, College of Science, Nanjing University of Technology, Nanjing 210009, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 27;66(Pt 12):m1682. doi: 10.1107/S1600536810048634.
In the title complex, CdCl(2)(C(4)H(8)O(2)), two different Cd(II) ions are present, one in a general position and one with site symmetry 2. The Cd(II) ions are coordinated by two O atoms from two 1,4-dioxane ligands and four chloride anions in a slightly distorted octa-hedral geometry and is connected to neighboring Cd(II) ions by two bridging chloride anions, generating infinite linear chains along the a axis. These chains are further inter-connected by bridging 1,4-dioxane ligands, affording a three-dimensional network.
在标题配合物[CdCl₂(C₄H₈O₂)]ₙ中，存在两种不同的Cd(II)离子，一种处于一般位置，另一种具有2次位点对称性。Cd(II)离子由来自两个1,4 - 二氧六环配体的两个O原子和四个氯离子以略微扭曲的八面体几何构型配位，并通过两个桥连氯离子与相邻的Cd(II)离子相连，沿a轴生成无限的线性链。这些链通过桥连的1,4 - 二氧六环配体进一步相互连接，形成三维网络。
