Chou Wei-Lung, Yih Kuang-Hway, Lee Gene-Hsiang, Huang Yen-Hsiang, Wang Hsiao-Fen
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 17;66(Pt 12):o3193. doi: 10.1107/S1600536810046027.
The title compound, C(11)H(18)N(2)S(4), was unexpectedly obtained during studies on the reactivity of the complex tris-(acac-κ(2)O,O')gallium(III) (acac is acetyl-acetonate) with C(4)H(8)NCS(2)H in dichloro-methane. The title compound shows disordered two pyrrolidine rings with major and minor occupancies of 0.546 (4) and 0.454 (4). Two (pyrrolidin-1-yl)carbothio-ylsulfanyl units are linked together through a methyl-ene C atom and weak C-H⋯S inter-actions are found.
标题化合物C(11)H(18)N(2)S(4)是在研究三(乙酰丙酮-κ(2)O,O')镓(III)(acac为乙酰丙酮)与C(4)H(8)NCS(2)H在二氯甲烷中的反应活性时意外得到的。标题化合物显示出两个吡咯烷环无序,主要占有率和次要占有率分别为0.546 (4)和0.454 (4)。两个(吡咯烷-1-基)羰基硫代硫烷基单元通过一个亚甲基C原子相连,并且发现了弱的C-H⋯S相互作用。